Effect of geometric parameters of substituted malonate anions on coordination environment of CuII atoms coordinated with 2,2′;6′,2″-terpyridine
Publication type: Journal Article
Publication date: 2014-12-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Structural data for known and newly obtained copper(II) complexes with 2,2′;6′,2″-terpyridine and substituted malonic (dimethylmalonic, 1,1-cyclopropane- and 1,1-cyclobutanedicarboxylic) acid dianions R2mal2- were used to show that the coordination environment of the metallocenter depends on the (O2C)C—C—C(CO2) angle. A chelate coordination of the R2mal2- dianion is realized for 1,1-cyclopropanedicarboxylate anion (~122.9°), while the dimethylmalonate and 1,1-cyclobutanedicarboxylate anions (107.4–110.8°) are characterized by a monodentate coordination.
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Gogoleva N. V. et al. Effect of geometric parameters of substituted malonate anions on coordination environment of CuII atoms coordinated with 2,2′;6′,2″-terpyridine // Russian Chemical Bulletin. 2014. Vol. 63. No. 12. pp. 2741-2747.
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Gogoleva N. V., Zorina-Tikhonova E. N., Kiskin M. A., Sidorov A. A., Eremenko I. L. Effect of geometric parameters of substituted malonate anions on coordination environment of CuII atoms coordinated with 2,2′;6′,2″-terpyridine // Russian Chemical Bulletin. 2014. Vol. 63. No. 12. pp. 2741-2747.
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TY - JOUR
DO - 10.1007/s11172-014-0809-y
UR - https://doi.org/10.1007/s11172-014-0809-y
TI - Effect of geometric parameters of substituted malonate anions on coordination environment of CuII atoms coordinated with 2,2′;6′,2″-terpyridine
T2 - Russian Chemical Bulletin
AU - Gogoleva, N. V.
AU - Zorina-Tikhonova, E. N.
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2014
DA - 2014/12/01
PB - Springer Nature
SP - 2741-2747
IS - 12
VL - 63
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2014_Gogoleva,
author = {N. V. Gogoleva and E. N. Zorina-Tikhonova and M. A. Kiskin and A. A. Sidorov and I. L. Eremenko},
title = {Effect of geometric parameters of substituted malonate anions on coordination environment of CuII atoms coordinated with 2,2′;6′,2″-terpyridine},
journal = {Russian Chemical Bulletin},
year = {2014},
volume = {63},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/s11172-014-0809-y},
number = {12},
pages = {2741--2747},
doi = {10.1007/s11172-014-0809-y}
}
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MLA
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Gogoleva, N. V., et al. “Effect of geometric parameters of substituted malonate anions on coordination environment of CuII atoms coordinated with 2,2′;6′,2″-terpyridine.” Russian Chemical Bulletin, vol. 63, no. 12, Dec. 2014, pp. 2741-2747. https://doi.org/10.1007/s11172-014-0809-y.