Effect of mercaptoethanol on the hydrocarbon oxidation and cis—trans-isomerization of unsaturated lipids
Publication type: Journal Article
Publication date: 2015-04-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The kinetics of the oxidation of ethylbenzene, limonene, and methyl linoleate containing mercaptoethanol additives were studied, as well as cis—trans-isomerization of the double bonds in methyl linoleate. Mercaptoethanol (RSH) additives were found to accelerate the oxidation of hydrocarbons and methyl linoleate due to the reaction of RSH with hydroperoxides (primary oxidation products) resulting in a low yield of free radicals. The cis—trans-isomerization catalyzed by thiyl radicals produced in the exchange radical reactions with RSH decelerates in the presence of oxygen.
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Mengele E. A., Krugovov D. A., Kasaikina O. T. Effect of mercaptoethanol on the hydrocarbon oxidation and cis—trans-isomerization of unsaturated lipids // Russian Chemical Bulletin. 2015. Vol. 64. No. 4. pp. 846-851.
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Mengele E. A., Krugovov D. A., Kasaikina O. T. Effect of mercaptoethanol on the hydrocarbon oxidation and cis—trans-isomerization of unsaturated lipids // Russian Chemical Bulletin. 2015. Vol. 64. No. 4. pp. 846-851.
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RIS
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TY - JOUR
DO - 10.1007/s11172-015-0943-1
UR - https://doi.org/10.1007/s11172-015-0943-1
TI - Effect of mercaptoethanol on the hydrocarbon oxidation and cis—trans-isomerization of unsaturated lipids
T2 - Russian Chemical Bulletin
AU - Mengele, E A
AU - Krugovov, D A
AU - Kasaikina, O T
PY - 2015
DA - 2015/04/01
PB - Springer Nature
SP - 846-851
IS - 4
VL - 64
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2015_Mengele,
author = {E A Mengele and D A Krugovov and O T Kasaikina},
title = {Effect of mercaptoethanol on the hydrocarbon oxidation and cis—trans-isomerization of unsaturated lipids},
journal = {Russian Chemical Bulletin},
year = {2015},
volume = {64},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-015-0943-1},
number = {4},
pages = {846--851},
doi = {10.1007/s11172-015-0943-1}
}
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MLA
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Mengele, E. A., et al. “Effect of mercaptoethanol on the hydrocarbon oxidation and cis—trans-isomerization of unsaturated lipids.” Russian Chemical Bulletin, vol. 64, no. 4, Apr. 2015, pp. 846-851. https://doi.org/10.1007/s11172-015-0943-1.