Springer Nature
Russian Chemical Bulletin
,  том 64 ,  издание 11 ,  страницы 2678-2689

Functionalized mercaptoacetic and propionic acid amides: synthesis, cyclopalladation features, and catalytic activity of metal complexes

Тип публикации: Journal Article
Дата публикации: 2015-11-01
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SJR: 0.272
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Impact factor: 1.7
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
Upon treatment with thiophenol or neomenthyl mercaptane, chloroacetand propionamides with an additional Nor S-donor substituent in the amine part gave new multidentate ligands readily undergoing direct cyclopalladation in the reaction with PdCl2(NCPh)2. The realization of κ3-X, N, S-coordination (X = N, S) in the complexes obtained was confirmed by IR and NMR spectroscopy and, in some cases, by single-crystal X-ray crystallography. The evaluation of catalytic activity of the palladocycles in the Suzuki cross-coupling of aryl bromides with PhB(OH)2 allowed us to establish the principal structure—activity correlations.
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Churusova S. G. et al. Functionalized mercaptoacetic and propionic acid amides: synthesis, cyclopalladation features, and catalytic activity of metal complexes // Russian Chemical Bulletin. 2015. Vol. 64. No. 11. pp. 2678-2689.
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Churusova S. G., Aleksanyan D. V., Klemenkova Z. S., Nelyubina Yu. V., Artyushin O. I., Vasilev A. A., Kozlov V. A., Sudarikov D. V., Rubtsova S. A. Functionalized mercaptoacetic and propionic acid amides: synthesis, cyclopalladation features, and catalytic activity of metal complexes // Russian Chemical Bulletin. 2015. Vol. 64. No. 11. pp. 2678-2689.
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TY - JOUR
DO - 10.1007/s11172-015-1207-9
UR - https://doi.org/10.1007/s11172-015-1207-9
TI - Functionalized mercaptoacetic and propionic acid amides: synthesis, cyclopalladation features, and catalytic activity of metal complexes
T2 - Russian Chemical Bulletin
AU - Churusova, S G
AU - Aleksanyan, D V
AU - Klemenkova, Z S
AU - Nelyubina, Yu V
AU - Artyushin, O I
AU - Vasilev, A. A.
AU - Kozlov, V. A.
AU - Sudarikov, D V
AU - Rubtsova, S A
PY - 2015
DA - 2015/11/01
PB - Springer Nature
SP - 2678-2689
IS - 11
VL - 64
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2015_Churusova,
author = {S G Churusova and D V Aleksanyan and Z S Klemenkova and Yu V Nelyubina and O I Artyushin and A. A. Vasilev and V. A. Kozlov and D V Sudarikov and S A Rubtsova},
title = {Functionalized mercaptoacetic and propionic acid amides: synthesis, cyclopalladation features, and catalytic activity of metal complexes},
journal = {Russian Chemical Bulletin},
year = {2015},
volume = {64},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s11172-015-1207-9},
number = {11},
pages = {2678--2689},
doi = {10.1007/s11172-015-1207-9}
}
MLA
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Churusova, S. G., et al. “Functionalized mercaptoacetic and propionic acid amides: synthesis, cyclopalladation features, and catalytic activity of metal complexes.” Russian Chemical Bulletin, vol. 64, no. 11, Nov. 2015, pp. 2678-2689. https://doi.org/10.1007/s11172-015-1207-9.
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