Springer Nature
Russian Chemical Bulletin
,  volume 64 ,  issue 12 ,  pages 2776-2779

Triboluminescence of zirconium η5-complexes

Publication type: Journal Article
Publication date: 2015-12-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
This work describes a comparative study of tribo- and photoluminescence of metallocenes (Cp2HfCl2, Cp2TiCl2, Cp2ZrCl2, (CpMe)2ZrCl2, rac-Me2C(3-But-Cp)2ZrCl2, Ind*2ZrCl2). Occurring under mechanodestruction of polycrystals, triboluminescence of zirconium bis-cyclopentadienyl complexes, Cp2ZrCl2, (CpMe)2ZrCl2, and rac-Me2C(3-But-Cp)2ZrCl2 has been revealed for the first time. The triboluminescence spectrum in air is similar to the photoluminescence spectrum of zirconocene polycrystals. The triboluminescence spectrum does not show *N2 luminescence. Ne and Ar lines are observed in the triboluminescence spectrum in the atmosphere of these gases. An increase in the number of substituents in zirconocene ligands leads to a bathochromic shift of the emission band maximum in triboluminescence spectra of the complexes. Possible mechanisms of zirconocene triboluminescence excitation are discussed.
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GOST Copy
Sharipov G. L. et al. Triboluminescence of zirconium η5-complexes // Russian Chemical Bulletin. 2015. Vol. 64. No. 12. pp. 2776-2779.
GOST all authors (up to 50) Copy
Sharipov G. L., Tukhbatullin A. A., Kovyazin P. V., Parfenova L. V., Ivchenko P. V., Nifantev I. E. Triboluminescence of zirconium η5-complexes // Russian Chemical Bulletin. 2015. Vol. 64. No. 12. pp. 2776-2779.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s11172-015-1224-8
UR - http://link.springer.com/10.1007/s11172-015-1224-8
TI - Triboluminescence of zirconium η5-complexes
T2 - Russian Chemical Bulletin
AU - Sharipov, G L
AU - Tukhbatullin, A A
AU - Kovyazin, P V
AU - Parfenova, L V
AU - Ivchenko, P V
AU - Nifantev, I E
PY - 2015
DA - 2015/12/01
PB - Springer Nature
SP - 2776-2779
IS - 12
VL - 64
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2015_Sharipov,
author = {G L Sharipov and A A Tukhbatullin and P V Kovyazin and L V Parfenova and P V Ivchenko and I E Nifantev},
title = {Triboluminescence of zirconium η5-complexes},
journal = {Russian Chemical Bulletin},
year = {2015},
volume = {64},
publisher = {Springer Nature},
month = {dec},
url = {http://link.springer.com/10.1007/s11172-015-1224-8},
number = {12},
pages = {2776--2779},
doi = {10.1007/s11172-015-1224-8}
}
MLA
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MLA Copy
Sharipov, G. L., et al. “Triboluminescence of zirconium η5-complexes.” Russian Chemical Bulletin, vol. 64, no. 12, Dec. 2015, pp. 2776-2779. http://link.springer.com/10.1007/s11172-015-1224-8.