Russian Chemical Bulletin

, том 64 , издание 12 , страницы 2954-2957

A catalytic system for the selective conversion of cellulose to 5-hydroxymethylfurfural under mild conditions

Тип публикации: Journal Article

Дата публикации: 2015-12-01

Springer Nature

Russian Chemical Bulletin

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SJR: 0.305

CiteScore: 2.8

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ISSN: 10665285, 15739171

DOI: 10.1007/s11172-015-1253-3

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General Chemistry

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Conversion of cellulose to 5-hydroxymethylfurfural (5-HMF), one of the most promising products derived by conversion of renewable raw materials, has been studied. When performing the process in ionic liquids, addition of small amounts of Brønsted acids was found to allow the adaption of the catalytic system to be used under mild conditions, which is particularly important for the industrial processing of cellulose. Highest yield of 5-HMF (44%) was obtained by carrying out the conversion of cellulose at 100 °C for 12 h with a modified catalytic system based on CrCl3·6H2O and H2SO4.

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Галкин Константин

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к.х.н., доц.

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Институт органической химии им. Н.Д. Зелинского РАН

Московский физико-технический институт

Московский политехнический университет

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Galkin K. I., Krivodaeva Е. А., Ananikov V. P. A catalytic system for the selective conversion of cellulose to 5-hydroxymethylfurfural under mild conditions // Russian Chemical Bulletin. 2015. Vol. 64. No. 12. pp. 2954-2957.

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TY - JOUR

DO - 10.1007/s11172-015-1253-3

UR - https://doi.org/10.1007/s11172-015-1253-3

TI - A catalytic system for the selective conversion of cellulose to 5-hydroxymethylfurfural under mild conditions

T2 - Russian Chemical Bulletin

AU - Galkin, K I

AU - Krivodaeva, Е А

AU - Ananikov, Valentine P

PY - 2015

DA - 2015/12/01

PB - Springer Nature

SP - 2954-2957

IS - 12

VL - 64

SN - 1066-5285

SN - 1573-9171

ER -

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@article{2015_Galkin,

author = {K I Galkin and Е А Krivodaeva and Valentine P Ananikov},

title = {A catalytic system for the selective conversion of cellulose to 5-hydroxymethylfurfural under mild conditions},

journal = {Russian Chemical Bulletin},

year = {2015},

volume = {64},

publisher = {Springer Nature},

month = {dec},

url = {https://doi.org/10.1007/s11172-015-1253-3},

number = {12},

pages = {2954--2957},

doi = {10.1007/s11172-015-1253-3}

}

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Galkin, K. I., et al. “A catalytic system for the selective conversion of cellulose to 5-hydroxymethylfurfural under mild conditions.” Russian Chemical Bulletin, vol. 64, no. 12, Dec. 2015, pp. 2954-2957. https://doi.org/10.1007/s11172-015-1253-3.