Heterometallic trinuclear {CdII—MII—CdII} pivalates (M = Mg, Ca, or Sr): ways of assembly and structural features
N. V. Gogoleva
1
,
M. A. Shmelev
1
,
I S Evstifeev
1
,
S A Nikolaevskii
1
,
G.G. Aleksandrov
1
,
M. A. Kiskin
1
,
Zh V Dobrokhotova
1
,
A. A. Sidorov
1
,
Publication type: Journal Article
Publication date: 2016-01-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Conditions for chemical assembly of new heterometallic trinuclear pivalates [Cd2M(piv)6L2] (M = Mg, Ca, or Sr; piv is pivalate) were found. Reactions with the nonchelating ligand 2,4-lutidine (lut) gave the crystals of heterometallic complexes [Cd2M(piv)6(lut)2] (M = Mg (1), Ca (2), and Sr (3)). With the chelating ligand 1,10-phenanthroline (phen), only the homometallic dimer [Cd2(piv)4(phen)2] (4) was obtained under these conditions. Yet heterometallic trinuclear complexes with 1,10-phenanthroline ([Cd2Mg(piv)6(H2O)(phen)2] (5), [CaCd2(piv)6(phen)2] (6), and [Cd2Sr(piv)6(phen)2]∙2MeCN (7)) were synthesized by reactions of phen with complexes 1—3. For all the complexes obtained, the molecular and crystal structures as well as the details of their molecular architecture were determined. The thermal behavior of aqua complex 5 was studied by TG and DSC. The complex eliminated the water molecule between 130 and 180 °C with a high endothermic effect (Q = 101 kJ mol–1) due to (1) intramolecular hydrogen bonds that stabilize its molecular architecture and (2) subsequent structural rearrangements.
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GOST
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Gogoleva N. V. et al. Heterometallic trinuclear {CdII—MII—CdII} pivalates (M = Mg, Ca, or Sr): ways of assembly and structural features // Russian Chemical Bulletin. 2016. Vol. 65. No. 1. pp. 181-190.
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Gogoleva N. V., Shmelev M. A., Evstifeev I. S., Nikolaevskii S. A., Aleksandrov G., Kiskin M. A., Dobrokhotova Z. V., Sidorov A. A., Eremenko I. L. Heterometallic trinuclear {CdII—MII—CdII} pivalates (M = Mg, Ca, or Sr): ways of assembly and structural features // Russian Chemical Bulletin. 2016. Vol. 65. No. 1. pp. 181-190.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11172-016-1281-7
UR - https://doi.org/10.1007/s11172-016-1281-7
TI - Heterometallic trinuclear {CdII—MII—CdII} pivalates (M = Mg, Ca, or Sr): ways of assembly and structural features
T2 - Russian Chemical Bulletin
AU - Gogoleva, N. V.
AU - Shmelev, M. A.
AU - Evstifeev, I S
AU - Nikolaevskii, S A
AU - Aleksandrov, G.G.
AU - Kiskin, M. A.
AU - Dobrokhotova, Zh V
AU - Sidorov, A. A.
AU - Eremenko, I. L.
PY - 2016
DA - 2016/01/01
PB - Springer Nature
SP - 181-190
IS - 1
VL - 65
SN - 1066-5285
SN - 1573-9171
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Gogoleva,
author = {N. V. Gogoleva and M. A. Shmelev and I S Evstifeev and S A Nikolaevskii and G.G. Aleksandrov and M. A. Kiskin and Zh V Dobrokhotova and A. A. Sidorov and I. L. Eremenko},
title = {Heterometallic trinuclear {CdII—MII—CdII} pivalates (M = Mg, Ca, or Sr): ways of assembly and structural features},
journal = {Russian Chemical Bulletin},
year = {2016},
volume = {65},
publisher = {Springer Nature},
month = {jan},
url = {https://doi.org/10.1007/s11172-016-1281-7},
number = {1},
pages = {181--190},
doi = {10.1007/s11172-016-1281-7}
}
Cite this
MLA
Copy
Gogoleva, N. V., et al. “Heterometallic trinuclear {CdII—MII—CdII} pivalates (M = Mg, Ca, or Sr): ways of assembly and structural features.” Russian Chemical Bulletin, vol. 65, no. 1, Jan. 2016, pp. 181-190. https://doi.org/10.1007/s11172-016-1281-7.