Bimetallic 3d—4f-molecules [MEu(ButCOO)5(1,10-phen)] (M = Zn2+, Co2+, phen is phenanthroline): synthesis, structure, luminescent and magnetic properties
M. A. Kiskin
1
,
Zh V Dobrokhotova
1
,
A S Bogomyakov
2
,
S A Kozyukhin
1, 3
,
V. Yu. Timoshenko
3, 4
,
Publication type: Journal Article
Publication date: 2016-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
New heterometallic complexes [MEu(Piv)5(1,10-phen)]•MeCN (M = Zn2+ (1), Co2+ (2), Piv– = ButCOO–, 1,10-phen is 1,10-phenanthroline) were obtained. Luminescence spectra of compound 1 reveal a metal-centered Eu3+ luminescence, the luminescence lifetime is about 1 ms. Using TGA and DSC methods, it was shown that [ZnEu(Piv)5(1,10-phen)] is a stable binuclear molecule undergoing a structural transformation in the 210—230 °C temperature range, which leads to a partial transition of the sample into the glass state. Complex 2 does not exhibit luminescence due to the presence of high-spin cobalt(II) ions. The magnetic behavior of 2 according to calculations based on the molecular field model is determined by spin-orbit interactions of cobalt(II) and europium(III) ions.
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12
Total citations:
12
Citations from 2024:
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(16.66%)
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Kiskin M. A. et al. Bimetallic 3d—4f-molecules [MEu(ButCOO)5(1,10-phen)] (M = Zn2+, Co2+, phen is phenanthroline): synthesis, structure, luminescent and magnetic properties // Russian Chemical Bulletin. 2016. Vol. 65. No. 6. pp. 1488-1494.
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Kiskin M. A., Dobrokhotova Z. V., Bogomyakov A. S., Kozyukhin S. A., Timoshenko V. Y., Eremenko I. L. Bimetallic 3d—4f-molecules [MEu(ButCOO)5(1,10-phen)] (M = Zn2+, Co2+, phen is phenanthroline): synthesis, structure, luminescent and magnetic properties // Russian Chemical Bulletin. 2016. Vol. 65. No. 6. pp. 1488-1494.
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TY - JOUR
DO - 10.1007/s11172-016-1475-z
UR - https://doi.org/10.1007/s11172-016-1475-z
TI - Bimetallic 3d—4f-molecules [MEu(ButCOO)5(1,10-phen)] (M = Zn2+, Co2+, phen is phenanthroline): synthesis, structure, luminescent and magnetic properties
T2 - Russian Chemical Bulletin
AU - Kiskin, M. A.
AU - Dobrokhotova, Zh V
AU - Bogomyakov, A S
AU - Kozyukhin, S A
AU - Timoshenko, V. Yu.
AU - Eremenko, I. L.
PY - 2016
DA - 2016/06/01
PB - Springer Nature
SP - 1488-1494
IS - 6
VL - 65
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2016_Kiskin,
author = {M. A. Kiskin and Zh V Dobrokhotova and A S Bogomyakov and S A Kozyukhin and V. Yu. Timoshenko and I. L. Eremenko},
title = {Bimetallic 3d—4f-molecules [MEu(ButCOO)5(1,10-phen)] (M = Zn2+, Co2+, phen is phenanthroline): synthesis, structure, luminescent and magnetic properties},
journal = {Russian Chemical Bulletin},
year = {2016},
volume = {65},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-016-1475-z},
number = {6},
pages = {1488--1494},
doi = {10.1007/s11172-016-1475-z}
}
Cite this
MLA
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Kiskin, M. A., et al. “Bimetallic 3d—4f-molecules [MEu(ButCOO)5(1,10-phen)] (M = Zn2+, Co2+, phen is phenanthroline): synthesis, structure, luminescent and magnetic properties.” Russian Chemical Bulletin, vol. 65, no. 6, Jun. 2016, pp. 1488-1494. https://doi.org/10.1007/s11172-016-1475-z.