Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties
A A Sapianik
1
,
I A Lutsenko
2
,
M. A. Kiskin
2
,
A. A. Sidorov
2
,
I. L. Eremenko
2
,
D G Samsonenko
1, 3
,
D N Dybtsev
1, 3
,
V. P. Fedin
1, 3
Publication type: Journal Article
Publication date: 2016-11-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
A new heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] (1, piv = –O2CBut, py = pyridine) was synthesized. Its reaction with terephthalic acid (H2bdc) in N,N-dimethylacetamide (DMA) results in metal-organic coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction analysis. The structure of 2 has two types of channels (4×8 Å and 5×16 Å) that are occupied by coordinated and guest DMA molecules.
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Sapianik A. A. et al. Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties // Russian Chemical Bulletin. 2016. Vol. 65. No. 11. pp. 2601-2606.
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Sapianik A. A., Lutsenko I. A., Kiskin M. A., Sidorov A. A., Eremenko I. L., Samsonenko D. G., Dybtsev D. N., Fedin V. P. Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties // Russian Chemical Bulletin. 2016. Vol. 65. No. 11. pp. 2601-2606.
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TY - JOUR
DO - 10.1007/s11172-016-1624-4
UR - https://doi.org/10.1007/s11172-016-1624-4
TI - Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties
T2 - Russian Chemical Bulletin
AU - Sapianik, A A
AU - Lutsenko, I A
AU - Kiskin, M. A.
AU - Sidorov, A. A.
AU - Eremenko, I. L.
AU - Samsonenko, D G
AU - Dybtsev, D N
AU - Fedin, V. P.
PY - 2016
DA - 2016/11/01
PB - Springer Nature
SP - 2601-2606
IS - 11
VL - 65
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2016_Sapianik,
author = {A A Sapianik and I A Lutsenko and M. A. Kiskin and A. A. Sidorov and I. L. Eremenko and D G Samsonenko and D N Dybtsev and V. P. Fedin},
title = {Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties},
journal = {Russian Chemical Bulletin},
year = {2016},
volume = {65},
publisher = {Springer Nature},
month = {nov},
url = {https://doi.org/10.1007/s11172-016-1624-4},
number = {11},
pages = {2601--2606},
doi = {10.1007/s11172-016-1624-4}
}
Cite this
MLA
Copy
Sapianik, A. A., et al. “Heterometallic molecular complex [Co2Gd(NO3)(piv)6(py)2] and coordination polymer [{CoGd(dma)2}2(bdc)5]·4DMA: the synthesis, structure, and properties.” Russian Chemical Bulletin, vol. 65, no. 11, Nov. 2016, pp. 2601-2606. https://doi.org/10.1007/s11172-016-1624-4.