Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties
S A Nikolaevskii
1
,
M. A. Kiskin
1
,
A A Starikova
2
,
N. N. Efimov
1
,
A. A. Sidorov
1
,
V. M. Novotortsev
1
,
Publication type: Journal Article
Publication date: 2016-12-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Two novel binuclear nickel(II) complexes [Ni2(O2CR)4(2,3-lut)2] (O2CR is anion of 3,5-di(tert-butyl)benzoic acid (bzo, 1) and 4-hydroxy-3,5-di(tert-butyl)benzoic acid (hbzo, 2); 2,3-lut is 2,3-lutidine) with four carboxylate bridges were synthesized. The structure of complex 1 was determined by X-ray diffraction. Both dimers 1 and 2 were characterized by elemental analysis, IR spectroscopy, and magnetic measurements. The presence of the α-substituent in the apical lutidine ligand leads to a distortion of the geometry of the metal carboxylate core in complex 1 as a result of short steric contacts Me(Lut)…O(OOCR) (3.134(7) Å). This is apparently responsible for a considerable decrease in the exchange parameters of complexes 1 and 2 (J =–30.0 and–23.6 cm–1, respectively) as compared to known analogues. Density functional calculations of the structure and magnetic properties of 1 and 2 were carried out by the UB3LYP/6-31G(d,p) method.
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Nikolaevskii S. A. et al. Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties // Russian Chemical Bulletin. 2016. Vol. 65. No. 12. pp. 2812-2819.
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Nikolaevskii S. A., Kiskin M. A., Starikova A. A., Efimov N. N., Sidorov A. A., Novotortsev V. M., Eremenko I. L. Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties // Russian Chemical Bulletin. 2016. Vol. 65. No. 12. pp. 2812-2819.
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TY - JOUR
DO - 10.1007/s11172-016-1661-z
UR - https://doi.org/10.1007/s11172-016-1661-z
TI - Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties
T2 - Russian Chemical Bulletin
AU - Nikolaevskii, S A
AU - Kiskin, M. A.
AU - Starikova, A A
AU - Efimov, N. N.
AU - Sidorov, A. A.
AU - Novotortsev, V. M.
AU - Eremenko, I. L.
PY - 2016
DA - 2016/12/01
PB - Springer Nature
SP - 2812-2819
IS - 12
VL - 65
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2016_Nikolaevskii,
author = {S A Nikolaevskii and M. A. Kiskin and A A Starikova and N. N. Efimov and A. A. Sidorov and V. M. Novotortsev and I. L. Eremenko},
title = {Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties},
journal = {Russian Chemical Bulletin},
year = {2016},
volume = {65},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007/s11172-016-1661-z},
number = {12},
pages = {2812--2819},
doi = {10.1007/s11172-016-1661-z}
}
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MLA
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Nikolaevskii, S. A., et al. “Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties.” Russian Chemical Bulletin, vol. 65, no. 12, Dec. 2016, pp. 2812-2819. https://doi.org/10.1007/s11172-016-1661-z.