Ferrocene-containing tri- and tetranuclear cyclic copper(i) and silver(i) pyrazolates
A.A. Titov
1, 2
,
A F Smolyakov
1, 2
,
A.N Rodionov
1
,
I D Kosenko
1
,
E A Guseva
1
,
Ya. V. Zubavichus
3
,
O. A. Filippov
1
,
Publication type: Journal Article
Publication date: 2017-09-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
New tri- and tetranuclear macrocyclic silver(i) and copper(i) 3-ferrocenyl-5-(trifluoromethyl)pyrazolates were prepared: [{(3-((η5-C5H4)Fe(η5-C5H5))-5-(CF3)-Pz}M]3 (M = Cu (1), Ag (2)) and [{(3-(( η5-C5H4)Fe(η5-C5H5))-5-(CF3)-Pz}Cu]4 (3). The structures of compounds were established by X-ray diffraction analysis. In the crystalline state, a planar trinuclear silver-containing macrocycliс pyrazolate and a saddle-shaped tetranuclear copper-containing macrocycle are formed. The introduction of a bulky substituent, ferrocene, into the pyrazole ligand results in complete shielding of the acidic metal sites, which precludes the coordination of base molecules.
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Total citations:
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Citations from 2024:
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Titov A. et al. Ferrocene-containing tri- and tetranuclear cyclic copper(i) and silver(i) pyrazolates // Russian Chemical Bulletin. 2017. Vol. 66. No. 9. pp. 1563-1568.
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Titov A., Smolyakov A. F., Rodionov A., Kosenko I. D., Guseva E. A., Zubavichus Y. V., Dorovatovskii P. V., Filippov O. A., Shubina E. S. Ferrocene-containing tri- and tetranuclear cyclic copper(i) and silver(i) pyrazolates // Russian Chemical Bulletin. 2017. Vol. 66. No. 9. pp. 1563-1568.
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TY - JOUR
DO - 10.1007/s11172-017-1925-2
UR - https://doi.org/10.1007/s11172-017-1925-2
TI - Ferrocene-containing tri- and tetranuclear cyclic copper(i) and silver(i) pyrazolates
T2 - Russian Chemical Bulletin
AU - Titov, A.A.
AU - Smolyakov, A F
AU - Rodionov, A.N
AU - Kosenko, I D
AU - Guseva, E A
AU - Zubavichus, Ya. V.
AU - Dorovatovskii, P. V.
AU - Filippov, O. A.
AU - Shubina, E. S.
PY - 2017
DA - 2017/09/01
PB - Springer Nature
SP - 1563-1568
IS - 9
VL - 66
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2017_Titov,
author = {A.A. Titov and A F Smolyakov and A.N Rodionov and I D Kosenko and E A Guseva and Ya. V. Zubavichus and P. V. Dorovatovskii and O. A. Filippov and E. S. Shubina},
title = {Ferrocene-containing tri- and tetranuclear cyclic copper(i) and silver(i) pyrazolates},
journal = {Russian Chemical Bulletin},
year = {2017},
volume = {66},
publisher = {Springer Nature},
month = {sep},
url = {https://doi.org/10.1007/s11172-017-1925-2},
number = {9},
pages = {1563--1568},
doi = {10.1007/s11172-017-1925-2}
}
Cite this
MLA
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Titov, A.A., et al. “Ferrocene-containing tri- and tetranuclear cyclic copper(i) and silver(i) pyrazolates.” Russian Chemical Bulletin, vol. 66, no. 9, Sep. 2017, pp. 1563-1568. https://doi.org/10.1007/s11172-017-1925-2.