Novel representatives of 16-membered aminomethylphosphines with alkyl substituents at nitrogen and their gold(I) complexes
Тип публикации: Journal Article
Дата публикации: 2018-02-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
Novel 1,9-diaza-3,7,11,15-tetraphosphacyclohexadecanes with alkyl, arylalkyl, or heteroarylalkyl substituents at the endocyclic nitrogen atoms were synthesized by condensation of 1,3-bis(phenylphosphino)propane, formaldehyde, and primary amines. The reactions are stereoselective and result in the isomer with the RSSR configuration of the phosphorus atoms as the major product. The 16-membered tetrakis(phosphine) ligands form stable neutral tetranuclear complexes with gold(I). In these complexes, the 16-membered cyclic ligands retain their free-state conformations and the configuration of the chiral phosphorus atoms.
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Musina E. I. et al. Novel representatives of 16-membered aminomethylphosphines with alkyl substituents at nitrogen and their gold(I) complexes // Russian Chemical Bulletin. 2018. Vol. 67. No. 2. pp. 328-335.
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Musina E. I., Wittmann T. I., Lönnecke P., Hey Hawkins E., Karasik A. A., Sinyashin O. G. Novel representatives of 16-membered aminomethylphosphines with alkyl substituents at nitrogen and their gold(I) complexes // Russian Chemical Bulletin. 2018. Vol. 67. No. 2. pp. 328-335.
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TY - JOUR
DO - 10.1007/s11172-018-2078-7
UR - http://link.springer.com/10.1007/s11172-018-2078-7
TI - Novel representatives of 16-membered aminomethylphosphines with alkyl substituents at nitrogen and their gold(I) complexes
T2 - Russian Chemical Bulletin
AU - Musina, E I
AU - Wittmann, T I
AU - Lönnecke, P
AU - Hey Hawkins, E
AU - Karasik, A A
AU - Sinyashin, O G
PY - 2018
DA - 2018/02/01
PB - Springer Nature
SP - 328-335
IS - 2
VL - 67
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2018_Musina,
author = {E I Musina and T I Wittmann and P Lönnecke and E Hey Hawkins and A A Karasik and O G Sinyashin},
title = {Novel representatives of 16-membered aminomethylphosphines with alkyl substituents at nitrogen and their gold(I) complexes},
journal = {Russian Chemical Bulletin},
year = {2018},
volume = {67},
publisher = {Springer Nature},
month = {feb},
url = {http://link.springer.com/10.1007/s11172-018-2078-7},
number = {2},
pages = {328--335},
doi = {10.1007/s11172-018-2078-7}
}
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MLA
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Musina, E. I., et al. “Novel representatives of 16-membered aminomethylphosphines with alkyl substituents at nitrogen and their gold(I) complexes.” Russian Chemical Bulletin, vol. 67, no. 2, Feb. 2018, pp. 328-335. http://link.springer.com/10.1007/s11172-018-2078-7.