Chemical assembly of the heteronuclear pivalate complex with the LiI and FeIII ions
I А Lutsenko
1
,
М А Kiskin
1
,
G.G. Alexandrov
1
,
V.K Imshennik
2
,
Yu. V. Maksimov
2
,
A V Khoroshilov
1
,
A S Goloveshkin
3
,
А. А. Sidorov
1
,
I. L. Eremenko
1, 3
2
Publication type: Journal Article
Publication date: 2018-03-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The heteronuclear complex [Fe4Li2(O)2(Piv)10(H2O)2] (1, Piv is the pivalic acid anion) was obtained by refluxing FeIII pivalates with LiI pivalates in toluene and isolated as the 1•PhCH3 solvate with a toluene molecule. According to X-ray diffraction data, complex 1 contains the {Fe4Li2O2} core. The Mössbauer spectroscopy data indicate that the core comprises para magnetic FeIII ions in the high-spin state located in the symmetric octahedral environment of oxygen atoms. Thermolysis of 1 studied by simultaneous thermal analysis demonstrated thermal stability of the complex up to 225 °С. The main end product of thermolysis at 600 °С is the mixed oxide LiFe5O8.
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15
Total citations:
15
Citations from 2024:
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GOST
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Lutsenko I. А. et al. Chemical assembly of the heteronuclear pivalate complex with the LiI and FeIII ions // Russian Chemical Bulletin. 2018. Vol. 67. No. 3. pp. 449-454.
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Lutsenko I. А., Kiskin М. А., Alexandrov G., Imshennik V., Maksimov Y. V., Khoroshilov A. V., Goloveshkin A. S., Sidorov А. А., Eremenko I. L. Chemical assembly of the heteronuclear pivalate complex with the LiI and FeIII ions // Russian Chemical Bulletin. 2018. Vol. 67. No. 3. pp. 449-454.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1007/s11172-018-2091-x
UR - https://doi.org/10.1007/s11172-018-2091-x
TI - Chemical assembly of the heteronuclear pivalate complex with the LiI and FeIII ions
T2 - Russian Chemical Bulletin
AU - Lutsenko, I А
AU - Kiskin, М А
AU - Alexandrov, G.G.
AU - Imshennik, V.K
AU - Maksimov, Yu. V.
AU - Khoroshilov, A V
AU - Goloveshkin, A S
AU - Sidorov, А. А.
AU - Eremenko, I. L.
PY - 2018
DA - 2018/03/01
PB - Springer Nature
SP - 449-454
IS - 3
VL - 67
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2018_Lutsenko,
author = {I А Lutsenko and М А Kiskin and G.G. Alexandrov and V.K Imshennik and Yu. V. Maksimov and A V Khoroshilov and A S Goloveshkin and А. А. Sidorov and I. L. Eremenko},
title = {Chemical assembly of the heteronuclear pivalate complex with the LiI and FeIII ions},
journal = {Russian Chemical Bulletin},
year = {2018},
volume = {67},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1007/s11172-018-2091-x},
number = {3},
pages = {449--454},
doi = {10.1007/s11172-018-2091-x}
}
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MLA
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Lutsenko, I. А., et al. “Chemical assembly of the heteronuclear pivalate complex with the LiI and FeIII ions.” Russian Chemical Bulletin, vol. 67, no. 3, Mar. 2018, pp. 449-454. https://doi.org/10.1007/s11172-018-2091-x.