Chemistry of 1,2-diphospholide anions and 1,2-diphospholes
Publication type: Journal Article
Publication date: 2020-03-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The main trends in the chemistry of 1,2-diphosphacyclopentadienes (1,2-diphospholes) and their derivatives 1,2-diphosphacyclopentadienide anions (1,2-diphospholide anions) were systematized, analyzed, and generalized. Methods for the generation of 1,2-diphospholide anions and their reactions with organic and organoelement electrophiles, as well as with transition metal complexes, were considered. Particular attention was paid to the cycloaddition reactions of 1-alkyl-1,2-diphospholes to obtain polycyclic chiral phosphines. A comparative analysis of the reactivity of 1,2-diphospholes and 1,2-diphospholide anions with respect to other representatives of phosphacyclopentadienes and phosphacyclopentadienide anions was carried out. The potential of application of 1,2-diphosphacyclopentadiene derivatives for the design of materials with magnetic, catalytic, and optical properties was shown.
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Total citations:
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Citations from 2024:
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Bezkishko I. A., Zagidullin A. A., Milyukov V. A. Chemistry of 1,2-diphospholide anions and 1,2-diphospholes // Russian Chemical Bulletin. 2020. Vol. 69. No. 3. pp. 435-448.
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Bezkishko I. A., Zagidullin A. A., Milyukov V. A. Chemistry of 1,2-diphospholide anions and 1,2-diphospholes // Russian Chemical Bulletin. 2020. Vol. 69. No. 3. pp. 435-448.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11172-020-2782-y
UR - http://link.springer.com/10.1007/s11172-020-2782-y
TI - Chemistry of 1,2-diphospholide anions and 1,2-diphospholes
T2 - Russian Chemical Bulletin
AU - Bezkishko, I A
AU - Zagidullin, A A
AU - Milyukov, V. A.
PY - 2020
DA - 2020/03/01
PB - Springer Nature
SP - 435-448
IS - 3
VL - 69
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2020_Bezkishko,
author = {I A Bezkishko and A A Zagidullin and V. A. Milyukov},
title = {Chemistry of 1,2-diphospholide anions and 1,2-diphospholes},
journal = {Russian Chemical Bulletin},
year = {2020},
volume = {69},
publisher = {Springer Nature},
month = {mar},
url = {http://link.springer.com/10.1007/s11172-020-2782-y},
number = {3},
pages = {435--448},
doi = {10.1007/s11172-020-2782-y}
}
Cite this
MLA
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Bezkishko, I. A., et al. “Chemistry of 1,2-diphospholide anions and 1,2-diphospholes.” Russian Chemical Bulletin, vol. 69, no. 3, Mar. 2020, pp. 435-448. http://link.springer.com/10.1007/s11172-020-2782-y.
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