Stabilization of phosphorus in (1,2,3,4,5-pentaphenylphosphole)palladium
Publication type: Journal Article
Publication date: 2020-06-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Our quantum chemical calculations predicted high stability of a palladium complex with 1,2,3,4,5-pentaphenylphosphole (ppp). The ligand, ppp, is unstable in free state and readily oxidized in air when in solution. The complex Pd(ppp) was synthesized and detected by electrospray ionization mass spectrometry. A Fourier transform ion cyclotron resonance mass spectrometry study revealed the presence of the complex in a solution after six months storage of the solution in air, thus demonstrating the possibility to stabilize the phosphorus ligand by complexation with transition metal.
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Total citations:
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Pentsak E. O. et al. Stabilization of phosphorus in (1,2,3,4,5-pentaphenylphosphole)palladium // Russian Chemical Bulletin. 2020. Vol. 69. No. 6. pp. 1185-1188.
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Pentsak E. O., Galushko A. S., Shaydullin R. R., Ananikov V. P. Stabilization of phosphorus in (1,2,3,4,5-pentaphenylphosphole)palladium // Russian Chemical Bulletin. 2020. Vol. 69. No. 6. pp. 1185-1188.
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TY - JOUR
DO - 10.1007/s11172-020-2887-3
UR - https://doi.org/10.1007/s11172-020-2887-3
TI - Stabilization of phosphorus in (1,2,3,4,5-pentaphenylphosphole)palladium
T2 - Russian Chemical Bulletin
AU - Pentsak, E O
AU - Galushko, A S
AU - Shaydullin, R R
AU - Ananikov, V P
PY - 2020
DA - 2020/06/01
PB - Springer Nature
SP - 1185-1188
IS - 6
VL - 69
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2020_Pentsak,
author = {E O Pentsak and A S Galushko and R R Shaydullin and V P Ananikov},
title = {Stabilization of phosphorus in (1,2,3,4,5-pentaphenylphosphole)palladium},
journal = {Russian Chemical Bulletin},
year = {2020},
volume = {69},
publisher = {Springer Nature},
month = {jun},
url = {https://doi.org/10.1007/s11172-020-2887-3},
number = {6},
pages = {1185--1188},
doi = {10.1007/s11172-020-2887-3}
}
Cite this
MLA
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Pentsak, E. O., et al. “Stabilization of phosphorus in (1,2,3,4,5-pentaphenylphosphole)palladium.” Russian Chemical Bulletin, vol. 69, no. 6, Jun. 2020, pp. 1185-1188. https://doi.org/10.1007/s11172-020-2887-3.