Effect of the [2-(diphenylphosphorylmethoxy)phenyl]diphenylphosphine oxide derivative structures on the extraction and ion-selective properties toward rare-earth elements
I. S. Ivanova
1
,
A. B. Ilyukhin
1
,
E N Pyatova
1
,
S V Demin
2
,
E A Zhogin
3
,
G S Tsebrikova
2
,
V P Solovev
2
,
D V Baulin
2
,
V E Baulin
4
,
Publication type: Journal Article
Publication date: 2020-07-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The effect of structures of the derivatives of [2-(diphenylphosphorylmethoxy)phenyl]-diphenylphosphine oxide (L1) on the complexation properties toward rare-earth elements (REE) was studied. A new structural analogue of L1, isopropyl 2-(diphenylphosphorylmethoxy)benzoate (L3), was synthesized. The extraction of REE by the carboxylated podand L3 in a 1,1,7-trihydrododecafluoroheptanol—water system with the HNO3 concentration varied in a range from 1 to 6 mol L−1 was studied. The stability constants of the neodymium(iii) and erbium(iii) nitrate complexes with L3 and 1-(methoxydiphenylphosphoryl)-2-diphenylphosphoryl-4-ethylbenzene (L2) and of lutetium(iii) nitrate and chloride complexes with L2 in 1,1,7-trihydrododecafluorheptanol were determined. The properties of the membranes of the ion-selective electrodes based on L1, L2, and L3 toward REE cations were tested. The crystal structures of L3 and [NdL3(NO3)3(DMSO)2] were determined by X-ray diffraction analysis.
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Total citations:
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Ivanova I. S. et al. Effect of the [2-(diphenylphosphorylmethoxy)phenyl]diphenylphosphine oxide derivative structures on the extraction and ion-selective properties toward rare-earth elements // Russian Chemical Bulletin. 2020. Vol. 69. No. 7. pp. 1336-1343.
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Ivanova I. S., Ilyukhin A. B., Pyatova E. N., Demin S. V., Zhogin E. A., Tsebrikova G. S., Solovev V. P., Baulin D. V., Baulin V. E., Tsivadze A. Y. Effect of the [2-(diphenylphosphorylmethoxy)phenyl]diphenylphosphine oxide derivative structures on the extraction and ion-selective properties toward rare-earth elements // Russian Chemical Bulletin. 2020. Vol. 69. No. 7. pp. 1336-1343.
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TY - JOUR
DO - 10.1007/s11172-020-2907-3
UR - https://link.springer.com/10.1007/s11172-020-2907-3
TI - Effect of the [2-(diphenylphosphorylmethoxy)phenyl]diphenylphosphine oxide derivative structures on the extraction and ion-selective properties toward rare-earth elements
T2 - Russian Chemical Bulletin
AU - Ivanova, I. S.
AU - Ilyukhin, A. B.
AU - Pyatova, E N
AU - Demin, S V
AU - Zhogin, E A
AU - Tsebrikova, G S
AU - Solovev, V P
AU - Baulin, D V
AU - Baulin, V E
AU - Tsivadze, A. Yu.
PY - 2020
DA - 2020/07/01
PB - Springer Nature
SP - 1336-1343
IS - 7
VL - 69
SN - 1066-5285
SN - 1573-9171
ER -
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BibTex (up to 50 authors)
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@article{2020_Ivanova,
author = {I. S. Ivanova and A. B. Ilyukhin and E N Pyatova and S V Demin and E A Zhogin and G S Tsebrikova and V P Solovev and D V Baulin and V E Baulin and A. Yu. Tsivadze},
title = {Effect of the [2-(diphenylphosphorylmethoxy)phenyl]diphenylphosphine oxide derivative structures on the extraction and ion-selective properties toward rare-earth elements},
journal = {Russian Chemical Bulletin},
year = {2020},
volume = {69},
publisher = {Springer Nature},
month = {jul},
url = {https://link.springer.com/10.1007/s11172-020-2907-3},
number = {7},
pages = {1336--1343},
doi = {10.1007/s11172-020-2907-3}
}
Cite this
MLA
Copy
Ivanova, I. S., et al. “Effect of the [2-(diphenylphosphorylmethoxy)phenyl]diphenylphosphine oxide derivative structures on the extraction and ion-selective properties toward rare-earth elements.” Russian Chemical Bulletin, vol. 69, no. 7, Jul. 2020, pp. 1336-1343. https://link.springer.com/10.1007/s11172-020-2907-3.