Synthesis and study of N,N′-disubstituted derivatives of pyromellitic diimide
E A Komissarova
1, 2
,
V E Zhulanov
2
,
I G Mokrushin
2
,
A N Vasyanin
2
,
E V Shklyaeva
2
,
G. G. Abashev
1, 2
Publication type: Journal Article
Publication date: 2020-10-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
New N, N′-bis(4,6-dimethylpyrimidin-2-yl)- and N, N′-bis(2,3,5,6-tetrafluorophenyl)-substituted pyromellitic diimides were synthesized. Their properties were studied in comparison with the previously synthesized N, N′-bis(4-fluorophenyl)pyromellitic diimide. Thermogravimetry, UV spectroscopy, cyclic voltammetry, and quantum chemical calculations in the framework of the density functional theory were used to characterize the synthesized compounds. The introduction of the pyrimidine cycle significantly decreases the energy of the lowest unoccupied molecular orbital. The highest occupied molecular orbitals in all compounds synthesized are deep-lying (about −7 eV).
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Komissarova E. A. et al. Synthesis and study of N,N′-disubstituted derivatives of pyromellitic diimide // Russian Chemical Bulletin. 2020. Vol. 69. No. 10. pp. 1944-1948.
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Komissarova E. A., Zhulanov V. E., Mokrushin I. G., Vasyanin A. N., Shklyaeva E. V., Abashev G. G. Synthesis and study of N,N′-disubstituted derivatives of pyromellitic diimide // Russian Chemical Bulletin. 2020. Vol. 69. No. 10. pp. 1944-1948.
Cite this
RIS
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TY - JOUR
DO - 10.1007/s11172-020-2983-4
UR - http://link.springer.com/10.1007/s11172-020-2983-4
TI - Synthesis and study of N,N′-disubstituted derivatives of pyromellitic diimide
T2 - Russian Chemical Bulletin
AU - Komissarova, E A
AU - Zhulanov, V E
AU - Mokrushin, I G
AU - Vasyanin, A N
AU - Shklyaeva, E V
AU - Abashev, G. G.
PY - 2020
DA - 2020/10/01
PB - Springer Nature
SP - 1944-1948
IS - 10
VL - 69
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2020_Komissarova,
author = {E A Komissarova and V E Zhulanov and I G Mokrushin and A N Vasyanin and E V Shklyaeva and G. G. Abashev},
title = {Synthesis and study of N,N′-disubstituted derivatives of pyromellitic diimide},
journal = {Russian Chemical Bulletin},
year = {2020},
volume = {69},
publisher = {Springer Nature},
month = {oct},
url = {http://link.springer.com/10.1007/s11172-020-2983-4},
number = {10},
pages = {1944--1948},
doi = {10.1007/s11172-020-2983-4}
}
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MLA
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Komissarova, E. A., et al. “Synthesis and study of N,N′-disubstituted derivatives of pyromellitic diimide.” Russian Chemical Bulletin, vol. 69, no. 10, Oct. 2020, pp. 1944-1948. http://link.springer.com/10.1007/s11172-020-2983-4.