Gold anode corrosion in an aqueous solution of 2,2-dimethyl-1,3-diaminopropane
Publication type: Journal Article
Publication date: 2021-04-01
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
The kinetics and mechanism of corrosion of an Au anode in a weakly basic aqueous solution of 2,2-dimethyl-1,3-diaminopropane (2,2-DM-1,3-DAP) were studied by gravimetry and cyclic voltammetry. Scanning and transmission electron microscopy was used to determine that under galvanostatic conditions the products of anode corrosion are reduced on a steel cathode with the formation of not only an electrolytic Au deposition on the cathode, but also colloidal gold nanoparticles in the electrolyte medium. The product of the interaction of 2,2-DM-1,3-DAP with atmospheric CO2, namely, the carbamic acid internal salt 3-ammonio-2,2-dimethyl-propylcarbamate, was isolated from the reaction solution.
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Vedenyapina M. D. et al. Gold anode corrosion in an aqueous solution of 2,2-dimethyl-1,3-diaminopropane // Russian Chemical Bulletin. 2021. Vol. 70. No. 4. pp. 735-744.
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Vedenyapina M. D., Kuznetzov V. V., Dmitrenok A. S., Minyaev M. E., Makhova N. N., Kazakova M. M. Gold anode corrosion in an aqueous solution of 2,2-dimethyl-1,3-diaminopropane // Russian Chemical Bulletin. 2021. Vol. 70. No. 4. pp. 735-744.
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TY - JOUR
DO - 10.1007/s11172-021-3144-0
UR - https://doi.org/10.1007/s11172-021-3144-0
TI - Gold anode corrosion in an aqueous solution of 2,2-dimethyl-1,3-diaminopropane
T2 - Russian Chemical Bulletin
AU - Vedenyapina, M D
AU - Kuznetzov, V V
AU - Dmitrenok, A S
AU - Minyaev, M E
AU - Makhova, N N
AU - Kazakova, M M
PY - 2021
DA - 2021/04/01
PB - Springer Nature
SP - 735-744
IS - 4
VL - 70
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2021_Vedenyapina,
author = {M D Vedenyapina and V V Kuznetzov and A S Dmitrenok and M E Minyaev and N N Makhova and M M Kazakova},
title = {Gold anode corrosion in an aqueous solution of 2,2-dimethyl-1,3-diaminopropane},
journal = {Russian Chemical Bulletin},
year = {2021},
volume = {70},
publisher = {Springer Nature},
month = {apr},
url = {https://doi.org/10.1007/s11172-021-3144-0},
number = {4},
pages = {735--744},
doi = {10.1007/s11172-021-3144-0}
}
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MLA
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Vedenyapina, M. D., et al. “Gold anode corrosion in an aqueous solution of 2,2-dimethyl-1,3-diaminopropane.” Russian Chemical Bulletin, vol. 70, no. 4, Apr. 2021, pp. 735-744. https://doi.org/10.1007/s11172-021-3144-0.