Russian Chemical Bulletin, volume 70, issue 12, pages 2416-2421

Solvent extraction of lanthanides(iii) with mixtures of 1,3,5-tris(2-diphenylphosphoryl-4-ethylphenoxymethyl)benzene and 4-benzoyl-5-methyl-2-phenyl-3-pyrazolone

Publication typeJournal Article
Publication date2021-12-01
Quartile SCImago
Q3
Quartile WOS
Q3
Impact factor1.7
ISSN10665285, 15739171
General Chemistry
Abstract
1,3,5-Tris(2-diphenylphosphoryl-4-ethylphenoxymethyl)benzene (L′), a phosphorylcontaining tripodand, was synthesized for the first time in order to find extraction systems for efficient recovery of lanthanides. The main regularities of extraction of lanthanide(III) ions with mixtures of L′ and 4-benzoyl-5-methyl-2-phenyl-3-pyrazolone (HL) into CHCl3, 1,2-dichloroethane, toluene, and carbon tetrachloride from chloride solutions were elucidated. A significant synergistic effect, associated with the formation of hydrophobic mixed-ligand complexes of lanthanides(III), was found. The stoichiometry of the extracted complexes was determined by the equilibrium shift method. The equilibrium constants and values of the synergistic effect in the LnIII—L′—HL—dichloroethane system were calculated. The influence of the nature of the organic solvent and the composition of the aqueous phase on the efficiency of lanthanide(III) ion extraction into the organic phase was considered.

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Turanov A. et al. Solvent extraction of lanthanides(iii) with mixtures of 1,3,5-tris(2-diphenylphosphoryl-4-ethylphenoxymethyl)benzene and 4-benzoyl-5-methyl-2-phenyl-3-pyrazolone // Russian Chemical Bulletin. 2021. Vol. 70. No. 12. pp. 2416-2421.
GOST all authors (up to 50) Copy
Turanov A., Karandashev V. K., Baulin D. V., Baulin V. E., Tsivadze A. Y. Solvent extraction of lanthanides(iii) with mixtures of 1,3,5-tris(2-diphenylphosphoryl-4-ethylphenoxymethyl)benzene and 4-benzoyl-5-methyl-2-phenyl-3-pyrazolone // Russian Chemical Bulletin. 2021. Vol. 70. No. 12. pp. 2416-2421.
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TY - JOUR
DO - 10.1007/s11172-021-3361-6
UR - https://doi.org/10.1007%2Fs11172-021-3361-6
TI - Solvent extraction of lanthanides(iii) with mixtures of 1,3,5-tris(2-diphenylphosphoryl-4-ethylphenoxymethyl)benzene and 4-benzoyl-5-methyl-2-phenyl-3-pyrazolone
T2 - Russian Chemical Bulletin
AU - Turanov, A.N.
AU - Karandashev, V K
AU - Baulin, D V
AU - Baulin, V E
AU - Tsivadze, A. Yu.
PY - 2021
DA - 2021/12/01 00:00:00
PB - Springer Nature
SP - 2416-2421
IS - 12
VL - 70
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2021_Turanov
author = {A.N. Turanov and V K Karandashev and D V Baulin and V E Baulin and A. Yu. Tsivadze},
title = {Solvent extraction of lanthanides(iii) with mixtures of 1,3,5-tris(2-diphenylphosphoryl-4-ethylphenoxymethyl)benzene and 4-benzoyl-5-methyl-2-phenyl-3-pyrazolone},
journal = {Russian Chemical Bulletin},
year = {2021},
volume = {70},
publisher = {Springer Nature},
month = {dec},
url = {https://doi.org/10.1007%2Fs11172-021-3361-6},
number = {12},
pages = {2416--2421},
doi = {10.1007/s11172-021-3361-6}
}
MLA
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MLA Copy
Turanov, A.N., et al. “Solvent extraction of lanthanides(iii) with mixtures of 1,3,5-tris(2-diphenylphosphoryl-4-ethylphenoxymethyl)benzene and 4-benzoyl-5-methyl-2-phenyl-3-pyrazolone.” Russian Chemical Bulletin, vol. 70, no. 12, Dec. 2021, pp. 2416-2421. https://doi.org/10.1007%2Fs11172-021-3361-6.
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