Synthesis, structure, and magnetic properties of the iron(iii) iodide complex with the 3,5-di-tert-butylcatecholate ligand
Тип публикации: Journal Article
Дата публикации: 2022-07-01
scimago Q3
БС2
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Краткое описание
The reaction of iron(ii) iodide with 3,5-di-tert-butyl-o-benzoquinone (3,5-DBBQ) in anhydrous diethyl ether afforded the heteroleptic binuclear complex [Fe2I2(3,5-DBCat)2(Et2O)2] (1) (3,5-DBCat is 3,5-di-tert-butylcatecholate). The crystal structure of the newly synthesized compound 1 was determined by single-crystal X-ray diffraction analysis, and its phase purity was confirmed by powder X-ray diffraction. Quantum chemical calculations indicate that the iron(III) ions are in the high-spin state and the redox-active ligand is in the dianionic catecholate form. Magnetochemical measurements of 1 in the temperature range of 2–300 K revealed intramolecular antiferromagnetic exchange interactions between FeIII ions, which is consistent with quantum chemical calculations.
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Russian Chemical Bulletin
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Yambulatov D. S. et al. Synthesis, structure, and magnetic properties of the iron(iii) iodide complex with the 3,5-di-tert-butylcatecholate ligand // Russian Chemical Bulletin. 2022. Vol. 71. No. 7. pp. 1385-1393.
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Yambulatov D. S., Nikolaevskii S. A., Babeshkin K. A., Efimov N. N., Voronina J. K., Starikova A. A., Goloveshkin A. S., Kiskin M. A., Eremenko I. L. Synthesis, structure, and magnetic properties of the iron(iii) iodide complex with the 3,5-di-tert-butylcatecholate ligand // Russian Chemical Bulletin. 2022. Vol. 71. No. 7. pp. 1385-1393.
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TY - JOUR
DO - 10.1007/s11172-022-3544-9
UR - https://link.springer.com/10.1007/s11172-022-3544-9
TI - Synthesis, structure, and magnetic properties of the iron(iii) iodide complex with the 3,5-di-tert-butylcatecholate ligand
T2 - Russian Chemical Bulletin
AU - Yambulatov, D S
AU - Nikolaevskii, S A
AU - Babeshkin, K A
AU - Efimov, N. N.
AU - Voronina, J K
AU - Starikova, A A
AU - Goloveshkin, A S
AU - Kiskin, M. A.
AU - Eremenko, I. L.
PY - 2022
DA - 2022/07/01
PB - Springer Nature
SP - 1385-1393
IS - 7
VL - 71
SN - 1066-5285
SN - 1573-9171
ER -
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@article{2022_Yambulatov,
author = {D S Yambulatov and S A Nikolaevskii and K A Babeshkin and N. N. Efimov and J K Voronina and A A Starikova and A S Goloveshkin and M. A. Kiskin and I. L. Eremenko},
title = {Synthesis, structure, and magnetic properties of the iron(iii) iodide complex with the 3,5-di-tert-butylcatecholate ligand},
journal = {Russian Chemical Bulletin},
year = {2022},
volume = {71},
publisher = {Springer Nature},
month = {jul},
url = {https://link.springer.com/10.1007/s11172-022-3544-9},
number = {7},
pages = {1385--1393},
doi = {10.1007/s11172-022-3544-9}
}
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Yambulatov, D. S., et al. “Synthesis, structure, and magnetic properties of the iron(iii) iodide complex with the 3,5-di-tert-butylcatecholate ligand.” Russian Chemical Bulletin, vol. 71, no. 7, Jul. 2022, pp. 1385-1393. https://link.springer.com/10.1007/s11172-022-3544-9.