Potassium and cesium thiocyanate complexes with diphenyloxa-21-crown-7: Synthesis and vibration spectra. Selective properties of dipnehyloxa-21-crown-7

I. S. Ivanova 1
, 
A V Dorokhov 1
, 
E N Pyatova 1
, 
E. N. Galkina 1
, 
V. V. Yakshin 2
, 
A. Yu. Tsivadze 3
1
 
2
 
All-Russia Research Institute of Chemical Technology, Moscow, Russia | 
3
 
Publication type: Journal Article
Publication date: 2005-03-01
Springer Nature
scimago Q4
wos Q4
SJR: 0.189
CiteScore: 1.7
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
Novel K and Cs complexes with diphenyloxa-21-crown-7 (2,3,5,6-dibenzo-1,4,7,10,13,16,19-heptaoxacyclo-heneicosadiene-2,5; DPO21C7) are synthesized and isolated in a solid state, and their IR spectra (4000−400 cm−1) are studied. Only four ether O atoms of crown ether are involved in coordination. Conformation of a macrocycle in the complexes depends on the cation size. The potentiometric selectivity of diphenyloxa-21-crown-7 toward Cs+ ions was found to be the greatest.
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Ivanova I. S. et al. Potassium and cesium thiocyanate complexes with diphenyloxa-21-crown-7: Synthesis and vibration spectra. Selective properties of dipnehyloxa-21-crown-7 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2005. Vol. 31. No. 3. pp. 151-155.
GOST all authors (up to 50) Copy
Ivanova I. S., Dorokhov A. V., Pyatova E. N., Galkina E. N., Yakshin V. V., Tsivadze A. Y. Potassium and cesium thiocyanate complexes with diphenyloxa-21-crown-7: Synthesis and vibration spectra. Selective properties of dipnehyloxa-21-crown-7 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. 2005. Vol. 31. No. 3. pp. 151-155.
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TY - JOUR
DO - 10.1007/s11173-005-0066-6
UR - http://link.springer.com/10.1007/s11173-005-0066-6
TI - Potassium and cesium thiocyanate complexes with diphenyloxa-21-crown-7: Synthesis and vibration spectra. Selective properties of dipnehyloxa-21-crown-7
T2 - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
AU - Ivanova, I. S.
AU - Dorokhov, A V
AU - Pyatova, E N
AU - Galkina, E. N.
AU - Yakshin, V. V.
AU - Tsivadze, A. Yu.
PY - 2005
DA - 2005/03/01
PB - Springer Nature
SP - 151-155
IS - 3
VL - 31
SN - 1070-3284
SN - 1608-3318
ER -
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@article{2005_Ivanova,
author = {I. S. Ivanova and A V Dorokhov and E N Pyatova and E. N. Galkina and V. V. Yakshin and A. Yu. Tsivadze},
title = {Potassium and cesium thiocyanate complexes with diphenyloxa-21-crown-7: Synthesis and vibration spectra. Selective properties of dipnehyloxa-21-crown-7},
journal = {Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya},
year = {2005},
volume = {31},
publisher = {Springer Nature},
month = {mar},
url = {http://link.springer.com/10.1007/s11173-005-0066-6},
number = {3},
pages = {151--155},
doi = {10.1007/s11173-005-0066-6}
}
MLA
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MLA Copy
Ivanova, I. S., et al. “Potassium and cesium thiocyanate complexes with diphenyloxa-21-crown-7: Synthesis and vibration spectra. Selective properties of dipnehyloxa-21-crown-7.” Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, vol. 31, no. 3, Mar. 2005, pp. 151-155. http://link.springer.com/10.1007/s11173-005-0066-6.