Russian Journal of General Chemistry

, volume 75 , issue 10 , pages 1643-1647

Reaction of fluoro(phenyl)carbene with Schiff bases: Synthesis of 2-fluoro-2-phenylaziridines

E Yu Kusei ¹

M.S. Novikov ¹

A F Khlebnikov ¹

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St. Petersburg state University, St. Petersburg, Russia |

Publication type: Journal Article

Publication date: 2005-10-01

Pleiades Publishing

Russian Journal of General Chemistry

scimago Q4

wos Q4

SJR: 0.179

CiteScore: 1.4

Impact factor: 0.8

ISSN: 10703632, 16083350

DOI: 10.1007/s11176-005-0480-y

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General Chemistry

Abstract

Fluoro(phenyl)carbene generated by reaction of α-bromo-α-fluorotoluene with potassium tert-butoxide reacts with Schiff bases to afford the corresponding 2-fluoro-2-phenylaziridines. The latter were isolated in low yields due to their instability under the carbene generation conditions. Although the reaction of α,α-dibromo-α-fluorotoluene with zinc and lead involves formation of fluoro(phenyl)carbene, this procedure is not suitable for the synthesis of 2-fluoro-2-phenylaziridines.

Found

2 citations

Novikov Mikhail

DSc in Chemistry, associate professor

218 publications, 4 210 citations, 54 reviews

h-index: 33

Saint Petersburg State University

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Kusei E. Yu., Novikov M., Khlebnikov A. F. Reaction of fluoro(phenyl)carbene with Schiff bases: Synthesis of 2-fluoro-2-phenylaziridines // Russian Journal of General Chemistry. 2005. Vol. 75. No. 10. pp. 1643-1647.

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TY - JOUR

DO - 10.1007/s11176-005-0480-y

UR - https://doi.org/10.1007/s11176-005-0480-y

TI - Reaction of fluoro(phenyl)carbene with Schiff bases: Synthesis of 2-fluoro-2-phenylaziridines

T2 - Russian Journal of General Chemistry

AU - Kusei, E Yu

AU - Novikov, M.S.

AU - Khlebnikov, A F

PY - 2005

DA - 2005/10/01

PB - Pleiades Publishing

SP - 1643-1647

IS - 10

VL - 75

SN - 1070-3632

SN - 1608-3350

ER -

BibTex |

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@article{2005_Kusei,

author = {E Yu Kusei and M.S. Novikov and A F Khlebnikov},

title = {Reaction of fluoro(phenyl)carbene with Schiff bases: Synthesis of 2-fluoro-2-phenylaziridines},

journal = {Russian Journal of General Chemistry},

year = {2005},

volume = {75},

publisher = {Pleiades Publishing},

month = {oct},

url = {https://doi.org/10.1007/s11176-005-0480-y},

number = {10},

pages = {1643--1647},

doi = {10.1007/s11176-005-0480-y}

}

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Kusei, E. Yu., et al. “Reaction of fluoro(phenyl)carbene with Schiff bases: Synthesis of 2-fluoro-2-phenylaziridines.” Russian Journal of General Chemistry, vol. 75, no. 10, Oct. 2005, pp. 1643-1647. https://doi.org/10.1007/s11176-005-0480-y.