Nano Research, volume 8, issue 9, pages 3020-3026

Hole-doping of mechanically exfoliated graphene by confined hydration layers

Bollmann Tjeerd R. J. 1, 2
Temmen Matthias 2
Reichling Michael 2
1
 
Inorganic Materials Science, MESA+ Institute for Nanotechnology, Enschede, The Netherlands
2
 
Fachbereich Physik, Universität Osnabrück, Osnabrück, Germany
Publication typeJournal Article
Publication date2015-08-06
Journal: Nano Research
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor9.9
ISSN19980124, 19980000
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
General Materials Science
Electrical and Electronic Engineering
Abstract
By the use of non-contact atomic force microscopy (NC-AFM) and Kelvin probe force microscopy (KPFM), we measure the local surface potential of mechanically exfoliated graphene on the prototypical insulating hydrophilic substrate of CaF2(111). Hydration layers confined between the graphene and the CaF2 substrate, resulting from the graphene’s preparation under ambient conditions on the hydrophilic substrate surface, are found to electronically modify the graphene as the material’s electron density transfers from graphene to the hydration layer. Density functional theory (DFT) calculations predict that the first 2 to 3 water layers adjacent to the graphene hole-dope the graphene by several percent of a unit charge per unit cell.

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Bollmann T. R. J. et al. Hole-doping of mechanically exfoliated graphene by confined hydration layers // Nano Research. 2015. Vol. 8. No. 9. pp. 3020-3026.
GOST all authors (up to 50) Copy
Bollmann T. R. J., Antipina L. Yu., Temmen M., Reichling M., Sorokin P. B. Hole-doping of mechanically exfoliated graphene by confined hydration layers // Nano Research. 2015. Vol. 8. No. 9. pp. 3020-3026.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1007/s12274-015-0807-x
UR - https://doi.org/10.1007%2Fs12274-015-0807-x
TI - Hole-doping of mechanically exfoliated graphene by confined hydration layers
T2 - Nano Research
AU - Bollmann, Tjeerd R. J.
AU - Temmen, Matthias
AU - Reichling, Michael
AU - Sorokin, Pavel B.
AU - Antipina, Liubov Yu
PY - 2015
DA - 2015/08/06 00:00:00
PB - Springer Nature
SP - 3020-3026
IS - 9
VL - 8
SN - 1998-0124
SN - 1998-0000
ER -
BibTex |
Cite this
BibTex Copy
@article{2015_Bollmann,
author = {Tjeerd R. J. Bollmann and Matthias Temmen and Michael Reichling and Pavel B. Sorokin and Liubov Yu Antipina},
title = {Hole-doping of mechanically exfoliated graphene by confined hydration layers},
journal = {Nano Research},
year = {2015},
volume = {8},
publisher = {Springer Nature},
month = {aug},
url = {https://doi.org/10.1007%2Fs12274-015-0807-x},
number = {9},
pages = {3020--3026},
doi = {10.1007/s12274-015-0807-x}
}
MLA
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MLA Copy
Bollmann, Tjeerd R. J., et al. “Hole-doping of mechanically exfoliated graphene by confined hydration layers.” Nano Research, vol. 8, no. 9, Aug. 2015, pp. 3020-3026. https://doi.org/10.1007%2Fs12274-015-0807-x.
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