Open Access

Nano-Micro Letters, volume 14, issue 1, publication number 187

Revisiting the Role of Physical Confinement and Chemical Regulation of 3D Hosts for Dendrite-Free Li Metal Anode

Shufen Ye ¹

Xingjia Chen ¹

Rui Zhang ²

Yu Jiang ³

Fanyang Huang ¹

HUIJUAN HUANG ¹

Yu Yao ¹

Jiao Shuhong ¹

Xiang Chen ⁴

Qiang Zhang ⁴

Yan Yu ^{1, 5}

Hide authors affiliations Show authors affiliations: 5 affiliations

Hefei National Center for Physical Sciences at the Microscale, Department of Materials Science and Engineering, iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, People’s Republic of China |

Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing, People’s Republic of China |

School of Materials Science and Engineering, Anhui University, Hefei, People’s Republic of China |

⁴

Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing, People’s Republic of China |

⁵

National Synchrotron Radiation Laboratory, Hefei, People’s Republic of China |

Publication type: Journal Article

Publication date: 2022-09-14

Springer Nature

Journal: Nano-Micro Letters

Quartile SCImago

Quartile WOS

Impact factor: 26.6

ISSN: 23116706, 21505551

DOI: 10.1007/s40820-022-00932-3

Copy DOI

Surfaces, Coatings and Films

Electronic, Optical and Magnetic Materials

Electrical and Electronic Engineering

Abstract

Lithium metal anode has been demonstrated as the most promising anode for lithium batteries because of its high theoretical capacity, but infinite volume change and dendritic growth during Li electrodeposition have prevented its practical applications. Both physical morphology confinement and chemical adsorption/diffusion regulation are two crucial approaches to designing lithiophilic materials to alleviate dendrite of Li metal anode. However, their roles in suppressing dendrite growth for long-life Li anode are not fully understood yet. Herein, three different Ni-based nanosheet arrays (NiO-NS, Ni3N-NS, and Ni5P4-NS) on carbon cloth as proof-of-concept lithiophilic frameworks are proposed for Li metal anodes. The two-dimensional nanoarray is more promising to facilitate uniform Li+ flow and electric field. Compared with the NiO-NS and the Ni5P4-NS, the Ni3N-NS on carbon cloth after reacting with molten Li (Li-Ni/Li3N-NS@CC) can afford the strongest adsorption to Li+ and the most rapid Li+ diffusion path. Therefore, the Li-Ni/Li3N-NS@CC electrode realizes the lowest overpotential and the most excellent electrochemical performance (60 mA cm−2 and 60 mAh cm−2 for 1000 h). Furthermore, a remarkable full battery (LiFePO4||Li-Ni/Li3N-NS@CC) reaches 300 cycles at 2C. This research provides valuable insight into designing dendrite-free alkali metal batteries.

By date By citations

Top-30

Citations by journals

	1 2 3 4 5
Nano-Micro Letters	Nano-Micro Letters, 5, 16.13% Nano-Micro Letters 5 publications, 16.13%
Chemical Engineering Journal	Chemical Engineering Journal, 3, 9.68% Chemical Engineering Journal 3 publications, 9.68%
Advanced Functional Materials	Advanced Functional Materials, 2, 6.45% Advanced Functional Materials 2 publications, 6.45%
Journal of Power Sources	Journal of Power Sources, 2, 6.45% Journal of Power Sources 2 publications, 6.45%
New Carbon Materials	New Carbon Materials, 2, 6.45% New Carbon Materials 2 publications, 6.45%
Nano Energy	Nano Energy, 1, 3.23% Nano Energy 1 publication, 3.23%
Advanced Science	Advanced Science, 1, 3.23% Advanced Science 1 publication, 3.23%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 1, 3.23% Journal of Colloid and Interface Science 1 publication, 3.23%
Small	Small, 1, 3.23% Small 1 publication, 3.23%
Energy & Environmental Materials	Energy & Environmental Materials, 1, 3.23% Energy & Environmental Materials 1 publication, 3.23%
Energy and Environmental Science	Energy and Environmental Science, 1, 3.23% Energy and Environmental Science 1 publication, 3.23%
Industrial & Engineering Chemistry Research	Industrial & Engineering Chemistry Research, 1, 3.23% Industrial & Engineering Chemistry Research 1 publication, 3.23%
Science China Materials	Science China Materials, 1, 3.23% Science China Materials 1 publication, 3.23%
Journal of the American Chemical Society	Journal of the American Chemical Society, 1, 3.23% Journal of the American Chemical Society 1 publication, 3.23%
Angewandte Chemie	Angewandte Chemie, 1, 3.23% Angewandte Chemie 1 publication, 3.23%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 3.23% Angewandte Chemie - International Edition 1 publication, 3.23%
ACS Applied Nano Materials	ACS Applied Nano Materials, 1, 3.23% ACS Applied Nano Materials 1 publication, 3.23%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 3.23% Electrochemical Energy Reviews 1 publication, 3.23%
ChemSusChem	ChemSusChem, 1, 3.23% ChemSusChem 1 publication, 3.23%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 3.23% Journal of Materials Chemistry A 1 publication, 3.23%
Rare Metals	Rare Metals, 1, 3.23% Rare Metals 1 publication, 3.23%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.23% Russian Chemical Reviews 1 publication, 3.23%
	1 2 3 4 5

Citations by publishers

	1 2 3 4 5 6 7 8 9
Elsevier	Elsevier, 9, 29.03% Elsevier 9 publications, 29.03%
Springer Nature	Springer Nature, 8, 25.81% Springer Nature 8 publications, 25.81%
Wiley	Wiley, 8, 25.81% Wiley 8 publications, 25.81%
American Chemical Society (ACS)	American Chemical Society (ACS), 3, 9.68% American Chemical Society (ACS) 3 publications, 9.68%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 2, 6.45% Royal Society of Chemistry (RSC) 2 publications, 6.45%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.23% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.23%
	1 2 3 4 5 6 7 8 9

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[1,19,11],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["3.23","61.29","35.48"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Nano-Micro Letters","Chemical Engineering Journal","Advanced Functional Materials","Journal of Power Sources","New Carbon Materials","Nano Energy","Advanced Science","Journal of Colloid and Interface Science","Small","Energy & Environmental Materials","Energy and Environmental Science","Industrial & Engineering Chemistry Research","Science China Materials","Journal of the American Chemical Society","Angewandte Chemie","Angewandte Chemie - International Edition","ACS Applied Nano Materials","Electrochemical Energy Reviews","ChemSusChem","Journal of Materials Chemistry A","Rare Metals","Russian Chemical Reviews"],"ids":[7765,16275,7715,14844,26227,23236,4130,24202,9872,26479,10138,12141,23382,4813,25450,19215,1600,25884,6896,14919,18829,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[5,3,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[16.13,9.68,6.45,6.45,6.45,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23,3.23],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Springer Nature","Wiley","American Chemical Society (ACS)","Royal Society of Chemistry (RSC)","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,8,11,40,123,9422],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[9,8,8,3,2,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[29.03,25.81,25.81,9.68,6.45,3.23],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,17,11],"percentage":["3.23","54.84","35.48"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2,0],"percentage":["0","6.45","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0],"percentage":["0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,3,1],"percentage":["0","9.68","3.23"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[1,16,9],"percentage":["3.23","51.61","29.03"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,1],"percentage":["0","0","3.23"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Publication PDF

Metrics

Cite this

GOST |

Cite this

GOST Copy

Ye S. et al. Revisiting the Role of Physical Confinement and Chemical Regulation of 3D Hosts for Dendrite-Free Li Metal Anode // Nano-Micro Letters. 2022. Vol. 14. No. 1. 187

GOST all authors (up to 50) Copy

Ye S., Chen X., Zhang R., Jiang Yu., Huang F., HUANG H., Yao Yu., Shuhong J., Chen X., Zhang Q., Yu Y. Revisiting the Role of Physical Confinement and Chemical Regulation of 3D Hosts for Dendrite-Free Li Metal Anode // Nano-Micro Letters. 2022. Vol. 14. No. 1. 187

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1007/s40820-022-00932-3

UR - https://doi.org/10.1007/s40820-022-00932-3

TI - Revisiting the Role of Physical Confinement and Chemical Regulation of 3D Hosts for Dendrite-Free Li Metal Anode

T2 - Nano-Micro Letters

AU - Ye, Shufen

AU - Chen, Xingjia

AU - Zhang, Rui

AU - Jiang, Yu

AU - Huang, Fanyang

AU - HUANG, HUIJUAN

AU - Yao, Yu

AU - Shuhong, Jiao

AU - Chen, Xiang

AU - Zhang, Qiang

AU - Yu, Yan

PY - 2022

DA - 2022/09/14 00:00:00

PB - Springer Nature

IS - 1

VL - 14

SN - 2311-6706

SN - 2150-5551

ER -

BibTex

Cite this

BibTex Copy

@article{2022_Ye,

author = {Shufen Ye and Xingjia Chen and Rui Zhang and Yu Jiang and Fanyang Huang and HUIJUAN HUANG and Yu Yao and Jiao Shuhong and Xiang Chen and Qiang Zhang and Yan Yu},

title = {Revisiting the Role of Physical Confinement and Chemical Regulation of 3D Hosts for Dendrite-Free Li Metal Anode},

journal = {Nano-Micro Letters},

year = {2022},

volume = {14},

publisher = {Springer Nature},

month = {sep},

url = {https://doi.org/10.1007/s40820-022-00932-3},

number = {1},

doi = {10.1007/s40820-022-00932-3}

}

Found error?

Publisher

Springer Nature

Journal

Nano-Micro Letters

Quartile SCImago

Quartile WOS

Impact factor

26.6

ISSN

23116706 (Print)
21505551 (Electronic)