The mechanism of the polymerization of n.butyl acrylate initiated with N,N-diethyl dithiocarbamate derivatives
Publication type: Journal Article
Publication date: 1990-01-01
scimago Q1
wos Q1
SJR: 1.076
CiteScore: 10.2
Impact factor: 6.3
ISSN: 00143057, 18731945
Materials Chemistry
Organic Chemistry
General Physics and Astronomy
Polymers and Plastics
Abstract
The kinetics of the photo-initiated polymerization of n.butyl acrylate by p -xylylene bis-( N , N -diethyldithiocarbamate) have been investigated in order to check the living character of this polymerization initiated with an “iniferter”. The reaction shows some features of a living system viz. growth of the molecular weight during the reaction under chosen conditions (high [M]/[I] ratios) and preparation of block copolymers. This confirms the existence of a reversible termination reaction between the growing chains and the dithiocarbamyl radicals. However, evidence has been found for the intervention of side reactions (formation of tetraethylthiuram disulphide, and decrease of the functionality of the polymers during the polymerization), indicating that the polymerization is not strictly living.
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79
Total citations:
79
Citations from 2024:
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(6.33%)
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GOST
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Lambrinos P. et al. The mechanism of the polymerization of n.butyl acrylate initiated with N,N-diethyl dithiocarbamate derivatives // European Polymer Journal. 1990. Vol. 26. No. 10. pp. 1125-1135.
GOST all authors (up to 50)
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Lambrinos P., Tardi M., Polton A., Sigwalt P. The mechanism of the polymerization of n.butyl acrylate initiated with N,N-diethyl dithiocarbamate derivatives // European Polymer Journal. 1990. Vol. 26. No. 10. pp. 1125-1135.
Cite this
RIS
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TY - JOUR
DO - 10.1016/0014-3057(90)90014-U
UR - https://doi.org/10.1016/0014-3057(90)90014-U
TI - The mechanism of the polymerization of n.butyl acrylate initiated with N,N-diethyl dithiocarbamate derivatives
T2 - European Polymer Journal
AU - Lambrinos, P.
AU - Tardi, M
AU - Polton, A
AU - Sigwalt, P.
PY - 1990
DA - 1990/01/01
PB - Elsevier
SP - 1125-1135
IS - 10
VL - 26
SN - 0014-3057
SN - 1873-1945
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1990_Lambrinos,
author = {P. Lambrinos and M Tardi and A Polton and P. Sigwalt},
title = {The mechanism of the polymerization of n.butyl acrylate initiated with N,N-diethyl dithiocarbamate derivatives},
journal = {European Polymer Journal},
year = {1990},
volume = {26},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/0014-3057(90)90014-U},
number = {10},
pages = {1125--1135},
doi = {10.1016/0014-3057(90)90014-U}
}
Cite this
MLA
Copy
Lambrinos, P., et al. “The mechanism of the polymerization of n.butyl acrylate initiated with N,N-diethyl dithiocarbamate derivatives.” European Polymer Journal, vol. 26, no. 10, Jan. 1990, pp. 1125-1135. https://doi.org/10.1016/0014-3057(90)90014-U.