Hydrogenation of carbon monoxide by ruthenium complexes with iodide promoters: catalytic and mechanistic investigations
1
Union Carbide Corporation South Charleston, West Virginia 25303 U.S.A.
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Publication type: Journal Article
Publication date: 1983-07-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Carbon monoxide and hydrogen are converted into organic products, including methanol, ethylene glycol, and ethanol, by halide-promoted ruthenium catalysts in organic solvents. Iodide salts are exceptionally good promoters for this system. Spectroscopic and reaction studies have shown that two ruthenium complexes, HRu3(CO)11− and Ru(CO)3I3−, are present during catalysis and essential for optimum activity. Possible roles for the involvement of these complexes in catalysis are considered.
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75
Total citations:
75
Citations from 2024:
2
(2.66%)
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GOST
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Dombek B. D. Hydrogenation of carbon monoxide by ruthenium complexes with iodide promoters: catalytic and mechanistic investigations // Journal of Organometallic Chemistry. 1983. Vol. 250. No. 1. pp. 467-483.
GOST all authors (up to 50)
Copy
Dombek B. D. Hydrogenation of carbon monoxide by ruthenium complexes with iodide promoters: catalytic and mechanistic investigations // Journal of Organometallic Chemistry. 1983. Vol. 250. No. 1. pp. 467-483.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0022-328x(83)85070-0
UR - https://doi.org/10.1016/0022-328x(83)85070-0
TI - Hydrogenation of carbon monoxide by ruthenium complexes with iodide promoters: catalytic and mechanistic investigations
T2 - Journal of Organometallic Chemistry
AU - Dombek, B Duane
PY - 1983
DA - 1983/07/01
PB - Elsevier
SP - 467-483
IS - 1
VL - 250
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1983_Dombek,
author = {B Duane Dombek},
title = {Hydrogenation of carbon monoxide by ruthenium complexes with iodide promoters: catalytic and mechanistic investigations},
journal = {Journal of Organometallic Chemistry},
year = {1983},
volume = {250},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/0022-328x(83)85070-0},
number = {1},
pages = {467--483},
doi = {10.1016/0022-328x(83)85070-0}
}
Cite this
MLA
Copy
Dombek, B. Duane. “Hydrogenation of carbon monoxide by ruthenium complexes with iodide promoters: catalytic and mechanistic investigations.” Journal of Organometallic Chemistry, vol. 250, no. 1, Jul. 1983, pp. 467-483. https://doi.org/10.1016/0022-328x(83)85070-0.