Chemical Physics Letters

, том 355 , издание 1-2 , страницы 65-70

Intramolecular excimer and exciplex emission of 1,4-dipyrenyl substituted cyclohexasilane

Cornelis A. van Walree ¹

Veronica E.M. Kaats-Richters ¹

Leonardus W. Jenneskens ¹

Rene Williams ²

IVO H. M. VAN STOKKUM ³

Скрыть аффилиации авторов Показать аффилиации авторов: 3 аффилиации

Debye Institute, Department of Physical Organic Chemistry Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands. |

Molecular Photonic Materials, Institute of Molecular Chemistry, Faculty of Science, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands |

Faculty of Sciences, Vrije Universiteit Amsterdam, De Boelelaan 1081, 1081 HV Amsterdam, The Netherlands |

Тип публикации: Journal Article

Дата публикации: 2002-03-01

Elsevier

Chemical Physics Letters

scimago Q2

wos Q2

БС2

SJR: 0.546

CiteScore: 5.9

Impact factor: 3.1

ISSN: 00092614, 18734448

DOI: 10.1016/S0009-2614(02)00183-5

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Physical and Theoretical Chemistry

General Physics and Astronomy

Краткое описание

Intramolecular excimer emission is observed for cis-1,4-di(1-pyrenyl)decamethylcyclohexasilane in nonpolar solvents. Time-resolved fluorescence spectroscopy and kinetic modelling indicate that the driving force of excimer formation is very small, and that the process is governed by the flexibility of the silicon ring. In the polar solvent acetonitrile, photoinduced electron transfer occurs, with the cyclohexasilane ring acting as electron donor and the pyrenyl group as electron acceptor. 2002 Elsevier Science B.V. All rights reserved.

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van Walree C. A. et al. Intramolecular excimer and exciplex emission of 1,4-dipyrenyl substituted cyclohexasilane // Chemical Physics Letters. 2002. Vol. 355. No. 1-2. pp. 65-70.

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van Walree C. A., Kaats-Richters V. E., Jenneskens L. W., Williams R., VAN STOKKUM I. H. M. Intramolecular excimer and exciplex emission of 1,4-dipyrenyl substituted cyclohexasilane // Chemical Physics Letters. 2002. Vol. 355. No. 1-2. pp. 65-70.

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TY - JOUR

DO - 10.1016/S0009-2614(02)00183-5

UR - https://doi.org/10.1016/S0009-2614(02)00183-5

TI - Intramolecular excimer and exciplex emission of 1,4-dipyrenyl substituted cyclohexasilane

T2 - Chemical Physics Letters

AU - van Walree, Cornelis A.

AU - Kaats-Richters, Veronica E.M.

AU - Jenneskens, Leonardus W.

AU - Williams, Rene

AU - VAN STOKKUM, IVO H. M.

PY - 2002

DA - 2002/03/01

PB - Elsevier

SP - 65-70

IS - 1-2

VL - 355

SN - 0009-2614

SN - 1873-4448

ER -

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@article{2002_van Walree,

author = {Cornelis A. van Walree and Veronica E.M. Kaats-Richters and Leonardus W. Jenneskens and Rene Williams and IVO H. M. VAN STOKKUM},

title = {Intramolecular excimer and exciplex emission of 1,4-dipyrenyl substituted cyclohexasilane},

journal = {Chemical Physics Letters},

year = {2002},

volume = {355},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/S0009-2614(02)00183-5},

number = {1-2},

pages = {65--70},

doi = {10.1016/S0009-2614(02)00183-5}

}

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van Walree, Cornelis A., et al. “Intramolecular excimer and exciplex emission of 1,4-dipyrenyl substituted cyclohexasilane.” Chemical Physics Letters, vol. 355, no. 1-2, Mar. 2002, pp. 65-70. https://doi.org/10.1016/S0009-2614(02)00183-5.

Издатель

Elsevier

Журнал

Chemical Physics Letters

scimago Q2

wos Q2

БС2

SJR

0.546

CiteScore

5.9

Impact factor

3.1

ISSN

00092614 (Print)

18734448

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