Photochemistry of chlorocarbonyl gold(I)
Publication type: Journal Article
Publication date: 1997-08-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The complex Au(CO)Cl shows a long wavelength absorption at λ max = 250nm which is assigned to a metal-centered ds transition. In the solid state this excited ds state is emissive (λ max = 663 nm) while in solution it is reactive. It is suggested that CO is released in the primary photochemical step. In CH 2 Cl 2 the photolysis of Au(CO)Cl leads finally to a disproportionation with the formation of AuCl 3 and metallic gold.
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GOST
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Kunkely H., Vogler A. Photochemistry of chlorocarbonyl gold(I) // Journal of Organometallic Chemistry. 1997. Vol. 541. No. 1-2. pp. 177-179.
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Kunkely H., Vogler A. Photochemistry of chlorocarbonyl gold(I) // Journal of Organometallic Chemistry. 1997. Vol. 541. No. 1-2. pp. 177-179.
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RIS
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TY - JOUR
DO - 10.1016/S0022-328X(97)00049-1
UR - https://doi.org/10.1016/S0022-328X(97)00049-1
TI - Photochemistry of chlorocarbonyl gold(I)
T2 - Journal of Organometallic Chemistry
AU - Kunkely, Horst
AU - Vogler, Arnd
PY - 1997
DA - 1997/08/01
PB - Elsevier
SP - 177-179
IS - 1-2
VL - 541
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1997_Kunkely,
author = {Horst Kunkely and Arnd Vogler},
title = {Photochemistry of chlorocarbonyl gold(I)},
journal = {Journal of Organometallic Chemistry},
year = {1997},
volume = {541},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/S0022-328X(97)00049-1},
number = {1-2},
pages = {177--179},
doi = {10.1016/S0022-328X(97)00049-1}
}
Cite this
MLA
Copy
Kunkely, Horst, and Arnd Vogler. “Photochemistry of chlorocarbonyl gold(I).” Journal of Organometallic Chemistry, vol. 541, no. 1-2, Aug. 1997, pp. 177-179. https://doi.org/10.1016/S0022-328X(97)00049-1.