Solubility of chelating agents and metal-containing compounds in supercritical fluid carbon dioxide
Тип публикации: Journal Article
Дата публикации: 1997-02-01
scimago Q1
wos Q1
white level БС1
SJR: 0.976
CiteScore: 11
Impact factor: 6.1
ISSN: 00399140, 18733573
PubMed ID:
18966727
Analytical Chemistry
Краткое описание
The solubility of 49 metal-containing compounds and 15 "free" ligands in supercritical fluid carbon dioxide is reviewed. Solubilities were found to range over eight orders of magnitude, with the highest value of solubility being 56 g l(-1). Metals complexed with fluorine substituted ligands were found to be the most soluble, and metals complexed with phenyl-substituted ligands the least soluble. A general trend for increasing solubility with increasing oxidation state is observed and this is correlated with the increased number of coordinating ligands protecting the metal center from interaction with the supercritical fluid and also due to the increased number of solvation interactions with the increased number of ligand groups.
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192
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192
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ГОСТ
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Smart N. Solubility of chelating agents and metal-containing compounds in supercritical fluid carbon dioxide // Talanta. 1997. Vol. 44. No. 2. pp. 137-150.
ГОСТ со всеми авторами (до 50)
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Smart N. Solubility of chelating agents and metal-containing compounds in supercritical fluid carbon dioxide // Talanta. 1997. Vol. 44. No. 2. pp. 137-150.
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RIS
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TY - JOUR
DO - 10.1016/S0039-9140(96)02008-5
UR - https://doi.org/10.1016/S0039-9140(96)02008-5
TI - Solubility of chelating agents and metal-containing compounds in supercritical fluid carbon dioxide
T2 - Talanta
AU - Smart, N.
PY - 1997
DA - 1997/02/01
PB - Elsevier
SP - 137-150
IS - 2
VL - 44
PMID - 18966727
SN - 0039-9140
SN - 1873-3573
ER -
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BibTex (до 50 авторов)
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@article{1997_Smart,
author = {N. Smart},
title = {Solubility of chelating agents and metal-containing compounds in supercritical fluid carbon dioxide},
journal = {Talanta},
year = {1997},
volume = {44},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/S0039-9140(96)02008-5},
number = {2},
pages = {137--150},
doi = {10.1016/S0039-9140(96)02008-5}
}
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MLA
Скопировать
Smart, N.. “Solubility of chelating agents and metal-containing compounds in supercritical fluid carbon dioxide.” Talanta, vol. 44, no. 2, Feb. 1997, pp. 137-150. https://doi.org/10.1016/S0039-9140(96)02008-5.
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