The effect of polar substituents on the conformation and stereochemistry of enolate radicals
2
Bio-Méga/Boehringer Ingelheim Research Inc., 2100 rue Cunard, Laval, Québec, Canada H7S 2G5.
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Publication type: Journal Article
Publication date: 1993-09-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
ESR measurements and AM1 calculations show that ester substituted radicals 2 and 6 prefer conformation A as a result of allylic strain effects. But dipolar repulsion between substituents X and CO2Et In 2 and 6 has a pronounced effect on the conformation and the stereoselectivity of radicals 2 and 6.
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Giese B. et al. The effect of polar substituents on the conformation and stereochemistry of enolate radicals // Tetrahedron Letters. 1993. Vol. 34. No. 37. pp. 5885-5888.
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Giese B., Damm W., Wetterich F., Zeitz H. G., Rancourt J., Guindon Y. The effect of polar substituents on the conformation and stereochemistry of enolate radicals // Tetrahedron Letters. 1993. Vol. 34. No. 37. pp. 5885-5888.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0040-4039(00)73805-6
UR - https://doi.org/10.1016/S0040-4039(00)73805-6
TI - The effect of polar substituents on the conformation and stereochemistry of enolate radicals
T2 - Tetrahedron Letters
AU - Giese, Bernd
AU - Damm, W.
AU - Wetterich, F
AU - Zeitz, H G
AU - Rancourt, J
AU - Guindon, Y.
PY - 1993
DA - 1993/09/01
PB - Elsevier
SP - 5885-5888
IS - 37
VL - 34
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
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@article{1993_Giese,
author = {Bernd Giese and W. Damm and F Wetterich and H G Zeitz and J Rancourt and Y. Guindon},
title = {The effect of polar substituents on the conformation and stereochemistry of enolate radicals},
journal = {Tetrahedron Letters},
year = {1993},
volume = {34},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/S0040-4039(00)73805-6},
number = {37},
pages = {5885--5888},
doi = {10.1016/S0040-4039(00)73805-6}
}
Cite this
MLA
Copy
Giese, B., et al. “The effect of polar substituents on the conformation and stereochemistry of enolate radicals.” Tetrahedron Letters, vol. 34, no. 37, Sep. 1993, pp. 5885-5888. https://doi.org/10.1016/S0040-4039(00)73805-6.