X-ray crystallographic studies provide additional evidence that an enzyme-like binding pocket is crucial to the enantioselective dihydroxylation of olefins by OsO4—bis-cinchona alkaloid complexes
Publication type: Journal Article
Publication date: 1994-05-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
X-Ray crystallographic analysis on single crystals and 1H NMR studies in solution of various bis-cinchona alkaloid derivatives reveal a general preference for a conformation which possesses a U-shaped binding pocket with favorable dimensions for the inclusion of olefinic substrates and the acceleration of face selective dihydroxylation by a proximate pentacoordinate OsO4.
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Corey E. J., Noe M. C., Sarshar S. X-ray crystallographic studies provide additional evidence that an enzyme-like binding pocket is crucial to the enantioselective dihydroxylation of olefins by OsO4—bis-cinchona alkaloid complexes // Tetrahedron Letters. 1994. Vol. 35. No. 18. pp. 2861-2864.
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Corey E. J., Noe M. C., Sarshar S. X-ray crystallographic studies provide additional evidence that an enzyme-like binding pocket is crucial to the enantioselective dihydroxylation of olefins by OsO4—bis-cinchona alkaloid complexes // Tetrahedron Letters. 1994. Vol. 35. No. 18. pp. 2861-2864.
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TY - JOUR
DO - 10.1016/S0040-4039(00)76644-5
UR - https://doi.org/10.1016/S0040-4039(00)76644-5
TI - X-ray crystallographic studies provide additional evidence that an enzyme-like binding pocket is crucial to the enantioselective dihydroxylation of olefins by OsO4—bis-cinchona alkaloid complexes
T2 - Tetrahedron Letters
AU - Corey, E J
AU - Noe, Mark C.
AU - Sarshar, Sepehr
PY - 1994
DA - 1994/05/01
PB - Elsevier
SP - 2861-2864
IS - 18
VL - 35
SN - 0040-4039
SN - 1873-3581
ER -
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@article{1994_Corey,
author = {E J Corey and Mark C. Noe and Sepehr Sarshar},
title = {X-ray crystallographic studies provide additional evidence that an enzyme-like binding pocket is crucial to the enantioselective dihydroxylation of olefins by OsO4—bis-cinchona alkaloid complexes},
journal = {Tetrahedron Letters},
year = {1994},
volume = {35},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/S0040-4039(00)76644-5},
number = {18},
pages = {2861--2864},
doi = {10.1016/S0040-4039(00)76644-5}
}
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Corey, E. J., et al. “X-ray crystallographic studies provide additional evidence that an enzyme-like binding pocket is crucial to the enantioselective dihydroxylation of olefins by OsO4—bis-cinchona alkaloid complexes.” Tetrahedron Letters, vol. 35, no. 18, May. 1994, pp. 2861-2864. https://doi.org/10.1016/S0040-4039(00)76644-5.