A mechanistically designed mono-cinchona alkaloid is an excellent catalyst for the enantioselective dihydroxylation of olefins
Publication type: Journal Article
Publication date: 1994-08-01
scimago Q3
wos Q3
SJR: 0.334
CiteScore: 3.2
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
On the basis of ideas recently advanced regarding the origin of enantioselectivity in the OsO 4 -promoted dihydroxylation of olefins catalyzed by bis-cinchona alkaloid derivatives such as 1 , specifically strong evidence for reaction via transition state assembly 2 , the mono-quinidine derivative 3 was selected as a promising catalytic ligand. The experimental observation of high enantioselectivity promoted by 3 provides additional evidence in favor of transition-state 2 . Graphic
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Corey E. J., Noe M. C., Grogan M. J. A mechanistically designed mono-cinchona alkaloid is an excellent catalyst for the enantioselective dihydroxylation of olefins // Tetrahedron Letters. 1994. Vol. 35. No. 35. pp. 6427-6430.
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Corey E. J., Noe M. C., Grogan M. J. A mechanistically designed mono-cinchona alkaloid is an excellent catalyst for the enantioselective dihydroxylation of olefins // Tetrahedron Letters. 1994. Vol. 35. No. 35. pp. 6427-6430.
Cite this
RIS
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TY - JOUR
DO - 10.1016/S0040-4039(00)78237-2
UR - https://doi.org/10.1016/S0040-4039(00)78237-2
TI - A mechanistically designed mono-cinchona alkaloid is an excellent catalyst for the enantioselective dihydroxylation of olefins
T2 - Tetrahedron Letters
AU - Corey, E J
AU - Noe, Mark C.
AU - Grogan, Michael J
PY - 1994
DA - 1994/08/01
PB - Elsevier
SP - 6427-6430
IS - 35
VL - 35
SN - 0040-4039
SN - 1873-3581
ER -
Cite this
BibTex (up to 50 authors)
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@article{1994_Corey,
author = {E J Corey and Mark C. Noe and Michael J Grogan},
title = {A mechanistically designed mono-cinchona alkaloid is an excellent catalyst for the enantioselective dihydroxylation of olefins},
journal = {Tetrahedron Letters},
year = {1994},
volume = {35},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/S0040-4039(00)78237-2},
number = {35},
pages = {6427--6430},
doi = {10.1016/S0040-4039(00)78237-2}
}
Cite this
MLA
Copy
Corey, E. J., et al. “A mechanistically designed mono-cinchona alkaloid is an excellent catalyst for the enantioselective dihydroxylation of olefins.” Tetrahedron Letters, vol. 35, no. 35, Aug. 1994, pp. 6427-6430. https://doi.org/10.1016/S0040-4039(00)78237-2.