Open Access
Efficient tunable approach for 5-(hydroxymethyl)furfural and 2,5-diformylfuran production from fructose in DMSO with bromide catalysis
Publication type: Journal Article
Publication date: 2024-01-04
scimago Q1
wos Q2
SJR: 0.811
CiteScore: 7.9
Impact factor: 4.3
ISSN: 15667367
General Chemistry
Catalysis
Process Chemistry and Technology
Abstract
This work describes a simple method for the preparation of 5-hydroxymethylfurfural (HMF) by dehydrating fructose in DMSO, either with the use of an affordable catalyst or in a catalyst-free manner. This process can be accompanied, under harsh conditions, by the bromide-catalyzed Kornblum oxidation of the hydroxyl group by the solvent, resulting in the formation of 2,5-diformylfuran (DFF). The optimized techniques presented in this study can serve as a foundation for the production of valuable biobased furanic platform chemicals from renewable sources in any laboratory, stimulating the development of sustainable chemistry and research in related fields worldwide.
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9
Total citations:
9
Citations from 2024:
9
(100%)
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Kolykhalov D. A. et al. Efficient tunable approach for 5-(hydroxymethyl)furfural and 2,5-diformylfuran production from fructose in DMSO with bromide catalysis // Catalysis Communications. 2024. Vol. 186. p. 106831.
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Kolykhalov D. A., Golysheva A. N., Karlinskii B. Ya. Efficient tunable approach for 5-(hydroxymethyl)furfural and 2,5-diformylfuran production from fructose in DMSO with bromide catalysis // Catalysis Communications. 2024. Vol. 186. p. 106831.
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TY - JOUR
DO - 10.1016/j.catcom.2023.106831
UR - https://linkinghub.elsevier.com/retrieve/pii/S1566736723002339
TI - Efficient tunable approach for 5-(hydroxymethyl)furfural and 2,5-diformylfuran production from fructose in DMSO with bromide catalysis
T2 - Catalysis Communications
AU - Kolykhalov, Denis A.
AU - Golysheva, Anastasia N.
AU - Karlinskii, Bogdan Ya
PY - 2024
DA - 2024/01/04
PB - Elsevier
SP - 106831
VL - 186
SN - 1566-7367
ER -
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@article{2024_Kolykhalov,
author = {Denis A. Kolykhalov and Anastasia N. Golysheva and Bogdan Ya Karlinskii},
title = {Efficient tunable approach for 5-(hydroxymethyl)furfural and 2,5-diformylfuran production from fructose in DMSO with bromide catalysis},
journal = {Catalysis Communications},
year = {2024},
volume = {186},
publisher = {Elsevier},
month = {jan},
url = {https://linkinghub.elsevier.com/retrieve/pii/S1566736723002339},
pages = {106831},
doi = {10.1016/j.catcom.2023.106831}
}