Enzyme catalysed deracemisation and dynamic kinetic resolution reactions
Publication type: Journal Article
Publication date: 2004-04-01
scimago Q1
wos Q1
SJR: 2.057
CiteScore: 12.7
Impact factor: 6.1
ISSN: 13675931, 18790402
PubMed ID:
15062770
Biochemistry
Analytical Chemistry
Abstract
New catalysts and reaction conditions have been developed for the dynamic kinetic resolution or deracemisation of racemic mixtures of chiral compounds. Specific functional groups that lend themselves particularly well to this approach include chiral secondary alcohols, alpha-amino acids, amines and carboxylic acids. A general theme of these processes is the combination of an enantioselective enzyme with a chemical reagent, the latter being used either to racemise the unreactive enantiomer or alternatively recycle an intermediate in the deracemisation process. In some examples of dynamic kinetic resolution, a second enzyme (racemase) is used to interconvert the enantiomers of the starting material.
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194
Total citations:
194
Citations from 2024:
7
(3%)
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GOST
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Turner N. A. Enzyme catalysed deracemisation and dynamic kinetic resolution reactions // Current Opinion in Chemical Biology. 2004. Vol. 8. No. 2. pp. 114-119.
GOST all authors (up to 50)
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Turner N. A. Enzyme catalysed deracemisation and dynamic kinetic resolution reactions // Current Opinion in Chemical Biology. 2004. Vol. 8. No. 2. pp. 114-119.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.cbpa.2004.02.001
UR - https://doi.org/10.1016/j.cbpa.2004.02.001
TI - Enzyme catalysed deracemisation and dynamic kinetic resolution reactions
T2 - Current Opinion in Chemical Biology
AU - Turner, Nicholas A.
PY - 2004
DA - 2004/04/01
PB - Elsevier
SP - 114-119
IS - 2
VL - 8
PMID - 15062770
SN - 1367-5931
SN - 1879-0402
ER -
Cite this
BibTex (up to 50 authors)
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@article{2004_Turner,
author = {Nicholas A. Turner},
title = {Enzyme catalysed deracemisation and dynamic kinetic resolution reactions},
journal = {Current Opinion in Chemical Biology},
year = {2004},
volume = {8},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.cbpa.2004.02.001},
number = {2},
pages = {114--119},
doi = {10.1016/j.cbpa.2004.02.001}
}
Cite this
MLA
Copy
Turner, Nicholas A.. “Enzyme catalysed deracemisation and dynamic kinetic resolution reactions.” Current Opinion in Chemical Biology, vol. 8, no. 2, Apr. 2004, pp. 114-119. https://doi.org/10.1016/j.cbpa.2004.02.001.