The beauty of binary phases: A facile strategy for synthesis, processing, functionalization, and application of ultrasmall metal nanoclusters
Publication type: Journal Article
Publication date: 2021-07-01
scimago Q1
wos Q1
SJR: 4.638
CiteScore: 38.2
Impact factor: 23.5
ISSN: 00108545, 18733840
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
• An overview of the two-phase strategies for ultrasmall metal nanoclusters. • The two-phase synthesis, processing, functionalization, and application of metal nanoclusters. • The challenges and prospects related to the two-phase strategies for metal nanoclusters. Ultrasmall metal nanoclusters (NCs) are a sub-class of metal nanoparticles (NPs) with a metal core size of ≤3 nm, and display interesting molecule-like properties. Atomically precise metal NCs can be synthesized by many solution chemistry methods in polar and non-polar reaction environments. Among these methods, two-phase based strategies involving a water-oil binary reaction system have emerged as a facile means to synthesize, process, functionalize, and apply metal NCs. This Review firstly presents an overview of the two-phase based strategies in the synthesis of hydrophobic and hydrophilic metal NCs, and aims to elucidate the underlying working principles of these strategies. Then, how a two-phase system could process metal NCs for size/composition tailoring, luminescence generation, sorting and purification is discussed. Subsequently, several examples that utilizing a two-phase system to efficiently functionalize metal NCs with different surface chemistry are highlighted. Finally, two-phase based applications of metal NCs in catalysis and self-assembly are also reviewed. The fundamentals and the advances of the two-phase based strategies in the synthesis, processing, functionalization, and application of metal NCs summarized in this Review may increase the acceptance of two-phase based strategy in the metal NC field.
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Total citations:
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Citations from 2024:
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(47.73%)
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Wang Z. et al. The beauty of binary phases: A facile strategy for synthesis, processing, functionalization, and application of ultrasmall metal nanoclusters // Coordination Chemistry Reviews. 2021. Vol. 438. p. 213900.
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Wang Z., Pan X., Qian S., Yang G., Du F., Yuan X. The beauty of binary phases: A facile strategy for synthesis, processing, functionalization, and application of ultrasmall metal nanoclusters // Coordination Chemistry Reviews. 2021. Vol. 438. p. 213900.
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TY - JOUR
DO - 10.1016/j.ccr.2021.213900
UR - https://doi.org/10.1016/j.ccr.2021.213900
TI - The beauty of binary phases: A facile strategy for synthesis, processing, functionalization, and application of ultrasmall metal nanoclusters
T2 - Coordination Chemistry Reviews
AU - Wang, Ziping
AU - Pan, Xinxin
AU - Qian, Shuyu
AU - Yang, Ge
AU - Du, Fanglin
AU - Yuan, Xun
PY - 2021
DA - 2021/07/01
PB - Elsevier
SP - 213900
VL - 438
SN - 0010-8545
SN - 1873-3840
ER -
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@article{2021_Wang,
author = {Ziping Wang and Xinxin Pan and Shuyu Qian and Ge Yang and Fanglin Du and Xun Yuan},
title = {The beauty of binary phases: A facile strategy for synthesis, processing, functionalization, and application of ultrasmall metal nanoclusters},
journal = {Coordination Chemistry Reviews},
year = {2021},
volume = {438},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.ccr.2021.213900},
pages = {213900},
doi = {10.1016/j.ccr.2021.213900}
}