Applied Clay Science, volume 163, pages 153-163

Optimising rational chemical analysis for quantitative determination of the composition of clay in soils

Vakalova Tatyana ¹

Pogrebenkov Valeriy ¹

Vereshagin Vladimir ¹

Khabas Tamara ¹

Revva Inna ¹

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Tomsk Polytechnic University, 30, Lenin Avenue, Tomsk,634050, Russia |

Publication type: Journal Article

Publication date: 2018-10-01

Elsevier

Journal: Applied Clay Science

Quartile SCImago

Quartile WOS

Impact factor: 5.6

ISSN: 01691317

DOI: 10.1016/j.clay.2018.07.014

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Geochemistry and Petrology

Geology

Abstract

A fractional (rational) chemical analytical method is proposed by which the material composition of clay rocks can be quantified and the clay-forming minerals present can be characterised. Subjecting raw clay to this procedure allows for the determination of the chemical composition of its fine-grained fraction, the amount and composition of exchangeable cations, water-soluble salts, carbonates and colloidal minerals, and the amount of amorphous silica and free quartz. A new, effective method is proposed for the qualitative and quantitative evaluation of the amorphous component in clays. This involves extracting colloids by treating the clay fractions with Tamm's reagent, a buffer solution of oxalic acid and ammonium oxalate with a pH of 3.25. Additionally, through calculations based on the results of chemical analyses, the illite content (derived from the content of non-exchangeable potassium oxide) and the chemical composition of the clay residue are determined. This enables the rock-forming clay mineral to be characterised and its structural chemical formula to be determined. This allows prediction of the physico-chemical and technological properties of the clay.

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	1
Environmental Science and Pollution Research	Environmental Science and Pollution Research, 1, 20% Environmental Science and Pollution Research 1 publication, 20%
Construction and Building Materials	Construction and Building Materials, 1, 20% Construction and Building Materials 1 publication, 20%
Journal of Environmental Management	Journal of Environmental Management, 1, 20% Journal of Environmental Management 1 publication, 20%
IEEE Transactions on Instrumentation and Measurement	IEEE Transactions on Instrumentation and Measurement, 1, 20% IEEE Transactions on Instrumentation and Measurement 1 publication, 20%
	1

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	1 2
Elsevier	Elsevier, 2, 40% Elsevier 2 publications, 40%
Springer Nature	Springer Nature, 1, 20% Springer Nature 1 publication, 20%
IEEE	IEEE, 1, 20% IEEE 1 publication, 20%
	1 2

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Vakalova T. et al. Optimising rational chemical analysis for quantitative determination of the composition of clay in soils // Applied Clay Science. 2018. Vol. 163. pp. 153-163.

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Vakalova T., Pogrebenkov V., Vereshagin V., Khabas T., Revva I. Optimising rational chemical analysis for quantitative determination of the composition of clay in soils // Applied Clay Science. 2018. Vol. 163. pp. 153-163.

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RIS Copy

TY - JOUR

DO - 10.1016/j.clay.2018.07.014

UR - https://doi.org/10.1016%2Fj.clay.2018.07.014

TI - Optimising rational chemical analysis for quantitative determination of the composition of clay in soils

T2 - Applied Clay Science

AU - Vakalova, Tatyana

AU - Pogrebenkov, Valeriy

AU - Vereshagin, Vladimir

AU - Khabas, Tamara

AU - Revva, Inna

PY - 2018

DA - 2018/10/01 00:00:00

PB - Elsevier

SP - 153-163

VL - 163

SN - 0169-1317

ER -

BibTex

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BibTex Copy

@article{2018_Vakalova,

author = {Tatyana Vakalova and Valeriy Pogrebenkov and Vladimir Vereshagin and Tamara Khabas and Inna Revva},

title = {Optimising rational chemical analysis for quantitative determination of the composition of clay in soils},

journal = {Applied Clay Science},

year = {2018},

volume = {163},

publisher = {Elsevier},

month = {oct},

url = {https://doi.org/10.1016%2Fj.clay.2018.07.014},

pages = {153--163},

doi = {10.1016/j.clay.2018.07.014}

}

Found error?

Publisher

Elsevier

Journal

Applied Clay Science

Quartile SCImago

Quartile WOS

Impact factor

5.6

ISSN

01691317 (Print)

Labs

Research Laboratory "Refractory non-metallic and silicate materials"

Profiles

Vereschagin, Vladimir I