Current Opinion in Electrochemistry, volume 33, pages 100931

Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects

Publication typeJournal Article
Publication date2022-06-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor8.5
ISSN24519103, 24519111
Analytical Chemistry
Electrochemistry
Abstract
In this review, we shortly summarize the basic theoretical milestones achieved in the mean-field theory of room temperature ionic liquids on charged electrodes since the publication of Kornyshev's seminal article in 2007. We pay special attention to the behavior of the differential capacitance profile and the microscopic parameters of ions that can have a substantial influence on it. Among them are parameters of short-range specific interactions, ionic diameters, static polarizabilities, and permanent dipole moments. We also discuss the recent ‘nonlocal’ mean-field theories that can describe the overscreening behavior of the local ionic concentrations, as well as the crossover from overscreening to crowding.

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Budkov Y. A., Kolesnikov A. L. Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects // Current Opinion in Electrochemistry. 2022. Vol. 33. p. 100931.
GOST all authors (up to 50) Copy
Budkov Y. A., Kolesnikov A. L. Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects // Current Opinion in Electrochemistry. 2022. Vol. 33. p. 100931.
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TY - JOUR
DO - 10.1016/j.coelec.2021.100931
UR - https://doi.org/10.1016%2Fj.coelec.2021.100931
TI - Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects
T2 - Current Opinion in Electrochemistry
AU - Budkov, Yury A.
AU - Kolesnikov, A L
PY - 2022
DA - 2022/06/01 00:00:00
PB - Elsevier
SP - 100931
VL - 33
SN - 2451-9103
SN - 2451-9111
ER -
BibTex
Cite this
BibTex Copy
@article{2022_Budkov,
author = {Yury A. Budkov and A L Kolesnikov},
title = {Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects},
journal = {Current Opinion in Electrochemistry},
year = {2022},
volume = {33},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016%2Fj.coelec.2021.100931},
pages = {100931},
doi = {10.1016/j.coelec.2021.100931}
}
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