Elsevier
Electrochimica Acta
,  volume 497 ,  pages 144479

Mechanistic aspects of glycerol oxidation on palladium electrocatalysts in model aqueous and fermentation media solutions

Publication type: Journal Article
Publication date: 2024-09-01
Elsevier
scimago Q1
wos Q1
SJR: 1.106
CiteScore: 10.6
Impact factor: 5.6
ISSN: 00134686, 18733859
Abstract
Herein, a study dealing with a progress on palladium (Pd) electrocatalysts for an efficient glycerol electrooxidation in model aqueous and real fermentation solutions with special focus on some physicochemical parameters (e.g., the impact of adsorption stage of multiple species, presence of oxygen, influence of anodic limits and Pd-size) was conducted. During the course of investigations by tandem of an optical oxygen minisensor and cyclic voltammetry a significant impact of oxygen on the efficiency of glycerol electrooxidation on Pd electrocatalysts at alkali pH in model aqueous and yeast fermentation media was revealed. The obtained knowledge was used for the optimization of an assay utilizing Pd-sensing layers for glycerol determination and quantification in yeast fermentation medium. Received results showed a satisfactory agreement with a control measurement carried out by gas chromatography mass-spectrometry.
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Silina Y. E. et al. Mechanistic aspects of glycerol oxidation on palladium electrocatalysts in model aqueous and fermentation media solutions // Electrochimica Acta. 2024. Vol. 497. p. 144479.
GOST all authors (up to 50) Copy
Silina Y. E., Butyrskaya E. V., Koch M., Fink-Straube C., Korkmaz N., Levchenko M. G., Zolotukhina E. V. Mechanistic aspects of glycerol oxidation on palladium electrocatalysts in model aqueous and fermentation media solutions // Electrochimica Acta. 2024. Vol. 497. p. 144479.
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RIS Copy
TY - JOUR
DO - 10.1016/j.electacta.2024.144479
UR - https://linkinghub.elsevier.com/retrieve/pii/S0013468624007205
TI - Mechanistic aspects of glycerol oxidation on palladium electrocatalysts in model aqueous and fermentation media solutions
T2 - Electrochimica Acta
AU - Silina, Y E
AU - Butyrskaya, E V
AU - Koch, M
AU - Fink-Straube, C.
AU - Korkmaz, Nuriye
AU - Levchenko, Maria G.
AU - Zolotukhina, Ekaterina V
PY - 2024
DA - 2024/09/01
PB - Elsevier
SP - 144479
VL - 497
SN - 0013-4686
SN - 1873-3859
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2024_Silina,
author = {Y E Silina and E V Butyrskaya and M Koch and C. Fink-Straube and Nuriye Korkmaz and Maria G. Levchenko and Ekaterina V Zolotukhina},
title = {Mechanistic aspects of glycerol oxidation on palladium electrocatalysts in model aqueous and fermentation media solutions},
journal = {Electrochimica Acta},
year = {2024},
volume = {497},
publisher = {Elsevier},
month = {sep},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0013468624007205},
pages = {144479},
doi = {10.1016/j.electacta.2024.144479}
}