European Polymer Journal, volume 162, pages 110917

Tetramethacrylic benzylidene cyclopentanone dye for one- and two-photon photopolymerization

Zhiganshina Elnara R ¹

Arsenyev Maxim V ¹

Chubich Dmytro A. ²

Kolymagin Danila A. ²

Pisarenko Anastasia V ²

Burkatovsky Dmitry S ²

Baranov Evgeny V ¹

Vitukhnovsky Alexei G. ^{2, 3}

Lobanov Andrew N ⁴

Matital Rilond P. ²

Aleynik Diana Ya ⁵

Chesnokov Sergey A.

Chesnokov Sergey ¹

Hide authors affiliations Show authors affiliations: 5 affiliations

G.A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Science (RAS) Tropinin st., 49, 603137, Nizhny Novgorod, Russia |

Moscow Institute of Physics and Technology (National Research University), Institutskii per. 9, 141700, Dolgoprudny, Russia |

Lebedev Physical Institute, Russian Academy of Sciences, Leninskii Prospect 53, 119991, Moscow Russia |

⁴

Lebedev Physical Institute, Russian Academy of Sciences, Leninskii Prospect 53, 119991 Moscow, Russia. |

⁵

Privolzhsky Research Medical University of the Ministry of Health Care of the Russian Federation, Minin and Pozharsky Sq. 10/1, 603950, Nizhny Novgorod, Russia |

Publication type: Journal Article

Publication date: 2022-01-01

Elsevier

Journal: European Polymer Journal

Quartile SCImago

Quartile WOS

Impact factor: 6

ISSN: 00143057

DOI: 10.1016/j.eurpolymj.2021.110917

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Materials Chemistry

Organic Chemistry

General Physics and Astronomy

Polymers and Plastics

Abstract

Using of new visible light crystalline one-component methacrylate-containing benzylidene cyclopentanone photoinitiator for curing pentaerythritol triacrylate monomer via one- and two-photon photopolymerization are investigated. • Polymerizable tetramethacrylic benzylidene cyclopentanone dye for one- and two-photon photopolymerization. The crystalline one-component methacrylate containing photoinitiator 4MetBAC was synthesized and characterized by 1 H NMR, 13 C NMR, IR-, UV–Vis spectrum, and X-Ray analysis. The one- and two-photon absorption, photoluminescence, and electrochemical properties of 4MetBAC in solution were investigated. The polymerization of PETA was induced directly by 4MetBAC (2.5–11.5 mM) under irradiation with LED@380 (1PP) or focused beam of femtosecond laser with wavelength 780 nm (2PP). The polymer nanostructures with intricate architecture («sleepers-rails»-, «cell scaffold»- and cylindrical spiral structures) were fabricated by the DLW method. The polymerization threshold of the composition based on 4Met-BAC (11.5 mM) was 0.9 mW at the recording speed of 170 μm/s. The smallest stable structures with the linear fragment sizes of 72 ± 5 nm (less than λ/10) have been obtained by nanolithography. Due to the polymerizable groups, 4Met-BAC has the ability to link into the polymer networks. Experiments with human dermal fibroblasts and cells of the HEK 293 line have been demonstrated that the final polymers prepared by both one- and two-photon photopolymerization (cell scaffold) are biosafety. Hence we believe that the PETA composition based on one-component methacrylate-containing photoinitiator 4Met-BAC opens up wide capabilities for creating three-dimensional topological structures with high submicron resolution by the DLW method for optoelectronic and biological applications.

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Zhiganshina E. R. et al. Tetramethacrylic benzylidene cyclopentanone dye for one- and two-photon photopolymerization // European Polymer Journal. 2022. Vol. 162. p. 110917.

GOST all authors (up to 50) Copy

Zhiganshina E. R., Arsenyev M. V., Chubich D. A., Kolymagin D. A., Pisarenko A. V., Burkatovsky D. S., Baranov E. V., Vitukhnovsky A. G., Lobanov A. N., Matital R. P., Aleynik D. Ya., Chesnokov S. A., Chesnokov S. Tetramethacrylic benzylidene cyclopentanone dye for one- and two-photon photopolymerization // European Polymer Journal. 2022. Vol. 162. p. 110917.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.eurpolymj.2021.110917

UR - https://doi.org/10.1016%2Fj.eurpolymj.2021.110917

TI - Tetramethacrylic benzylidene cyclopentanone dye for one- and two-photon photopolymerization

T2 - European Polymer Journal

AU - Zhiganshina, Elnara R

AU - Chubich, Dmytro A.

AU - Kolymagin, Danila A.

AU - Pisarenko, Anastasia V

AU - Burkatovsky, Dmitry S

AU - Lobanov, Andrew N

AU - Matital, Rilond P.

AU - Chesnokov, Sergey A.

AU - Arsenyev, Maxim V

AU - Baranov, Evgeny V

AU - Vitukhnovsky, Alexei G.

AU - Aleynik, Diana Ya

AU - Chesnokov, Sergey

PY - 2022

DA - 2022/01/01 00:00:00

PB - Elsevier

SP - 110917

VL - 162

SN - 0014-3057

ER -

BibTex

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BibTex Copy

@article{2022_Zhiganshina,

author = {Elnara R Zhiganshina and Dmytro A. Chubich and Danila A. Kolymagin and Anastasia V Pisarenko and Dmitry S Burkatovsky and Andrew N Lobanov and Rilond P. Matital and Sergey A. Chesnokov and Maxim V Arsenyev and Evgeny V Baranov and Alexei G. Vitukhnovsky and Diana Ya Aleynik and Sergey Chesnokov},

title = {Tetramethacrylic benzylidene cyclopentanone dye for one- and two-photon photopolymerization},

journal = {European Polymer Journal},

year = {2022},

volume = {162},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016%2Fj.eurpolymj.2021.110917},

pages = {110917},

doi = {10.1016/j.eurpolymj.2021.110917}

}

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Publisher

Elsevier

Journal

European Polymer Journal

Quartile SCImago

Quartile WOS

Impact factor

ISSN

00143057 (Print)

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Laboratory of 3D Printing technologies for functional Microstructures

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