Solubility of citric acid in water, ethanol, n-propanol and in mixtures of ethanol+water
Publication type: Journal Article
Publication date: 2013-08-01
scimago Q2
wos Q2
SJR: 0.578
CiteScore: 5.4
Impact factor: 2.7
ISSN: 03783812, 18790224
Physical and Theoretical Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
• The solubility of citric acid in water, ethanol, n-propanol and ethanol + water was systematically measured by a static analytical method. • For ternary systems, data were correlated as function of alcohol concentration for each temperature. • Regarding the pure solvents, both models demonstrated good agreement with the experimental data. • It was observed that adding ethanol in the water increased citric acid solubility in all cases. The solubility of citric acid or 3-carboxy-3-hydroxypentanedioic acid in water, ethanol, n-propanol and ethanol + water mixtures at temperatures ranging from 293.7 to 333.1 K was investigated. The experimental results obtained were correlated with the temperature for pure solvents by two equations based on the literature. For ternary systems, data were correlated as function of alcohol concentration for each temperature. Regarding the pure solvents, both of the models demonstrated good agreement with the experimental data. There are disagreements with the recent work published by Daneshfar et al. (2012) [12] . It was observed that adding ethanol in the water increased citric acid solubility in all cases.
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Total citations:
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Citations from 2024:
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Oliveira M. S., Malagoni R. A., Franco Júnior M. R. Solubility of citric acid in water, ethanol, n-propanol and in mixtures of ethanol+water // Fluid Phase Equilibria. 2013. Vol. 352. pp. 110-113.
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Oliveira M. S., Malagoni R. A., Franco Júnior M. R. Solubility of citric acid in water, ethanol, n-propanol and in mixtures of ethanol+water // Fluid Phase Equilibria. 2013. Vol. 352. pp. 110-113.
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TY - JOUR
DO - 10.1016/j.fluid.2013.05.014
UR - https://doi.org/10.1016/j.fluid.2013.05.014
TI - Solubility of citric acid in water, ethanol, n-propanol and in mixtures of ethanol+water
T2 - Fluid Phase Equilibria
AU - Oliveira, Mauro Schneider
AU - Malagoni, Ricardo A
AU - Franco Júnior, Moilton R.
PY - 2013
DA - 2013/08/01
PB - Elsevier
SP - 110-113
VL - 352
SN - 0378-3812
SN - 1879-0224
ER -
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BibTex (up to 50 authors)
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@article{2013_Oliveira,
author = {Mauro Schneider Oliveira and Ricardo A Malagoni and Moilton R. Franco Júnior},
title = {Solubility of citric acid in water, ethanol, n-propanol and in mixtures of ethanol+water},
journal = {Fluid Phase Equilibria},
year = {2013},
volume = {352},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.fluid.2013.05.014},
pages = {110--113},
doi = {10.1016/j.fluid.2013.05.014}
}