Inorganica Chimica Acta, volume 394, pages 328-336
Chemistry of vinylidene complexes. XXI. Synthesis, spectroscopic and structural study of the RePt and MnPt μ–vinylidene complexes
Antonova Alla B.
1
,
Verpekin Victor V.
1
,
Chudin Oleg S.
1
,
Vasiliev Alexander
2, 3
,
Pavlenko Nina I
1
,
Sokolenko William A
1
,
Rubaylo Anatoly I
4, 5
,
Semeikin Oleg V.
6
Publication type: Journal Article
Publication date: 2013-01-01
Journal:
Inorganica Chimica Acta
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The series of dinuclear μ–vinylidene complexes Cp(CO)2RePt(–C CHPh)(L 2 ) ( 2 – 5 ) were formed by consecutive reactions of Cp(CO) 2 Re C CHPh ( 1 ) with Pt(PPh3) 4 and Cp(CO) 2 RePt(μ–C CHPh)(PPh3) 2 ( 2 ) with diphosphines L 2 = dppm, dppe, dppp. The structures of Cp(CO) 2 MPt(–C CHPh)(dppp) (M = Mn, Re) were determined by single crystal XRD. The rotation of the [Cp(CO) 2 Re] and [PtP 2 ] fragments around the Re–Pt bond was discovered by VT NMR investigation. ► The series of dinuclear μ–vinylidene complexes Cp(CO) 2 RePt(μ–C CHPh)(L 2 ) (L 2 = (PPh 3 ) 2 , dppm, dppe, dppp) were synthesized and characterized. ► Dependence of the structural and spectroscopic parameters of complexes Cp(CO) 2 MPt(μ–C CHPh)(L 2 ) on the metal M = Mn, Re and ligands L 2 were investigated. ► The rotation of the Re- and Pt-containing fragments around the Re–Pt bond was shown by VT NMR study of Cp(CO) 2 RePt(μ–C CHPh)(L 2 ). Reaction of Cp(CO) 2 Re C CHPh ( 1 ) with Pt(PPh 3 ) 4 and subsequent treatment of Cp(CO) 2 RePt(μ–C CHPh)(PPh 3 ) 2 ( 2 ) with diphosphines P–P = dppe, dppp afforded new complexes Cp(CO) 2 RePt(μ–C CHPh)(P–P) ( 4 , 5 ). The structures of Cp(CO) 2 RePt(μ–C CHPh)(dppp) ( 5 ) and Cp(CO) 2 MnPt(μ–C CHPh)(dppp) ( 10 ) have been determined by single crystal XRD. The influence of the nature of M = Re, Mn and L 2 = (PPh 3 ) 2 , dppm, dppe, dppp at the Pt atom on the structural, IR and 1 H, 13 C and 31 P NMR spectroscopic characteristics of complexes Cp(CO) 2 MPt(μ–C CHPh)(L 2 ) ( 2 – 5 , 7 – 10 ) is considered.
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Antonova A. B. et al. Chemistry of vinylidene complexes. XXI. Synthesis, spectroscopic and structural study of the RePt and MnPt μ–vinylidene complexes // Inorganica Chimica Acta. 2013. Vol. 394. pp. 328-336.
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Antonova A. B., Verpekin V. V., Chudin O. S., Vasiliev A., Pavlenko N. I., Sokolenko W. A., Rubaylo A. I., Semeikin O. V. Chemistry of vinylidene complexes. XXI. Synthesis, spectroscopic and structural study of the RePt and MnPt μ–vinylidene complexes // Inorganica Chimica Acta. 2013. Vol. 394. pp. 328-336.
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TY - JOUR
DO - 10.1016/j.ica.2012.06.038
UR - https://doi.org/10.1016%2Fj.ica.2012.06.038
TI - Chemistry of vinylidene complexes. XXI. Synthesis, spectroscopic and structural study of the RePt and MnPt μ–vinylidene complexes
T2 - Inorganica Chimica Acta
AU - Antonova, Alla B.
AU - Verpekin, Victor V.
AU - Chudin, Oleg S.
AU - Vasiliev, Alexander
AU - Pavlenko, Nina I
AU - Sokolenko, William A
AU - Rubaylo, Anatoly I
AU - Semeikin, Oleg V.
PY - 2013
DA - 2013/01/01 00:00:00
PB - Elsevier
SP - 328-336
VL - 394
SN - 0020-1693
SN - 1873-3255
ER -
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@article{2013_Antonova,
author = {Alla B. Antonova and Victor V. Verpekin and Oleg S. Chudin and Alexander Vasiliev and Nina I Pavlenko and William A Sokolenko and Anatoly I Rubaylo and Oleg V. Semeikin},
title = {Chemistry of vinylidene complexes. XXI. Synthesis, spectroscopic and structural study of the RePt and MnPt μ–vinylidene complexes},
journal = {Inorganica Chimica Acta},
year = {2013},
volume = {394},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016%2Fj.ica.2012.06.038},
pages = {328--336},
doi = {10.1016/j.ica.2012.06.038}
}