Journal of Nuclear Materials, volume 532, pages 152073

Cenosphere-sourced hydrothermal synthesis of pollucite-analcime solid solutions as a low-temperature method to immobilize 137Cs in a mineral-like form

Vereshchagina T.A. ¹

Kutikhina Ekaterina A ¹

Chernykh Yana Yu ¹

Solovyov Leonid A. ¹

Zhizhaev Anatoly M. ¹

Vereshchagin S.N. ¹

Fomenko Elena V ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center “Krasnoyarsk Science Center SB RAS”, 50/24 Akademgorodok, Krasnoyarsk, 660036, Russia

Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of Sciences

Federal Research Center "Krasnoyarsk Science Center" of the Siberian Branch of the Russian Academy of Sciences

Publication type: Journal Article

Publication date: 2020-04-01

Elsevier

Journal: Journal of Nuclear Materials

Quartile SCImago

Quartile WOS

Impact factor: 3.1

ISSN: 00223115

DOI: 10.1016/j.jnucmat.2020.152073

Copy DOI

General Materials Science

Nuclear and High Energy Physics

Nuclear Energy and Engineering

Abstract

Two narrow fractions of coal fly ash cenospheres with ∼90 wt % glass phase and different Si/Al ratio (2.1 and 2.9 in the glass phase), shell porosity and thickness, globule size, and content of a mullite phase were used as a glassy source of Si and Al in the hydrothermal synthesis of pollucite-analcime solid solutions at 150 °C and autogenous pressure, 1.0 M NaOH, Cs/Na ratios of 0–0.25. Hollow microsphere globules of about 60–70 and 140–170 μm in sizes are produced as Cs immobilized forms in this process. The microspheres have a composite mullite/ANA wall, where ANA is analcime-pollucite solid solutions. Composition and morphology of solid products as well as composition of ANA phases were characterized by PXRD, SEM-EDS and STA methods. The influence of the mullite content and shell thickness on the preservation of the product spherical shape has been established. The degree of Cs+ recovery from alkaline solutions due to preferential involvement of cesium in the synthesis of ANA phases was up to 96%.

By date By citations

Citations by journals

	1
Materials	Materials, 1, 12.5% Materials 1 publication, 12.5%
Journal of Radioanalytical and Nuclear Chemistry	Journal of Radioanalytical and Nuclear Chemistry, 1, 12.5% Journal of Radioanalytical and Nuclear Chemistry 1 publication, 12.5%
Physics and Chemistry of Minerals	Physics and Chemistry of Minerals, 1, 12.5% Physics and Chemistry of Minerals 1 publication, 12.5%
Cement and Concrete Composites	Cement and Concrete Composites, 1, 12.5% Cement and Concrete Composites 1 publication, 12.5%
Advanced Powder Technology	Advanced Powder Technology, 1, 12.5% Advanced Powder Technology 1 publication, 12.5%
Materials Research Express	Materials Research Express, 1, 12.5% Materials Research Express 1 publication, 12.5%
Journal of Nuclear Materials	Journal of Nuclear Materials, 1, 12.5% Journal of Nuclear Materials 1 publication, 12.5%
Ceramics International	Ceramics International, 1, 12.5% Ceramics International 1 publication, 12.5%
	1

Citations by publishers

	1 2 3 4
Elsevier	Elsevier, 4, 50% Elsevier 4 publications, 50%
Springer Nature	Springer Nature, 2, 25% Springer Nature 2 publications, 25%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 12.5% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 12.5%
IOP Publishing	IOP Publishing, 1, 12.5% IOP Publishing 1 publication, 12.5%
	1 2 3 4

We do not take into account publications that without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2021,2022,2023,2024],"ids":[0,0,0,0],"codes":[0,0,0,0],"imageUrls":["","","",""],"datasets":[{"label":"Citations number","data":[3,3,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["37.5","37.5","12.5","12.5"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Materials","Journal of Radioanalytical and Nuclear Chemistry","Physics and Chemistry of Minerals","Cement and Concrete Composites","Advanced Powder Technology","Materials Research Express","Journal of Nuclear Materials","Ceramics International"],"ids":[25198,12902,7091,10332,4165,3993,21537,15103],"codes":[0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[12.5,12.5,12.5,12.5,12.5,12.5,12.5,12.5],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Springer Nature","Multidisciplinary Digital Publishing Institute (MDPI)","IOP Publishing"],"ids":[17,8,202,2075],"codes":[0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp"],"datasets":[{"label":"","data":[4,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[50,25,12.5,12.5],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Metrics

Cite this

GOST |

Cite this

GOST Copy

Vereshchagina T. et al. Cenosphere-sourced hydrothermal synthesis of pollucite-analcime solid solutions as a low-temperature method to immobilize 137Cs in a mineral-like form // Journal of Nuclear Materials. 2020. Vol. 532. p. 152073.

GOST all authors (up to 50) Copy

Vereshchagina T., Kutikhina E. A., Chernykh Y. Yu., Solovyov L. A., Zhizhaev A. M., Vereshchagin S., Fomenko E. V. Cenosphere-sourced hydrothermal synthesis of pollucite-analcime solid solutions as a low-temperature method to immobilize 137Cs in a mineral-like form // Journal of Nuclear Materials. 2020. Vol. 532. p. 152073.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.jnucmat.2020.152073

UR - https://doi.org/10.1016%2Fj.jnucmat.2020.152073

TI - Cenosphere-sourced hydrothermal synthesis of pollucite-analcime solid solutions as a low-temperature method to immobilize 137Cs in a mineral-like form

T2 - Journal of Nuclear Materials

AU - Vereshchagina, T.A.

AU - Kutikhina, Ekaterina A

AU - Chernykh, Yana Yu

AU - Solovyov, Leonid A.

AU - Zhizhaev, Anatoly M.

AU - Vereshchagin, S.N.

AU - Fomenko, Elena V

PY - 2020

DA - 2020/04/01 00:00:00

PB - Elsevier

SP - 152073

VL - 532

SN - 0022-3115

ER -

BibTex

Cite this

BibTex Copy

@article{2020_Vereshchagina,

author = {T.A. Vereshchagina and Ekaterina A Kutikhina and Yana Yu Chernykh and Leonid A. Solovyov and Anatoly M. Zhizhaev and S.N. Vereshchagin and Elena V Fomenko},

title = {Cenosphere-sourced hydrothermal synthesis of pollucite-analcime solid solutions as a low-temperature method to immobilize 137Cs in a mineral-like form},

journal = {Journal of Nuclear Materials},

year = {2020},

volume = {532},

publisher = {Elsevier},

month = {apr},

url = {https://doi.org/10.1016%2Fj.jnucmat.2020.152073},

pages = {152073},

doi = {10.1016/j.jnucmat.2020.152073}

}

Found error?

Publisher

Elsevier

Journal

Journal of Nuclear Materials

Quartile SCImago

Quartile WOS

Impact factor

3.1

ISSN

00223115 (Print)

Labs

Laboratory of Catalytic transformations of small molecules

Profiles