Journal of Organometallic Chemistry, volume 691, issue 24-25, pages 5444-5447

A pyridine-containing ruthenium–indenylidene complex: Synthesis and activity in ring-closing metathesis

HERVÉ CLAVIER 1
Jeffrey L. Petersen 2
1
 
Department of Chemistry, University of New Orleans, New Orleans, LA 70148, USA
2
 
Department of Chemistry, University of West Virginia, Morgantown, WV 26506-6045, USA
Publication typeJournal Article
Publication date2006-12-01
scimago Q3
SJR0.359
CiteScore4.4
Impact factor2.1
ISSN0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of Cl2Ru(PCy3)2(3-phenylindenylidene) with excess pyridine leads to the new pyridine-containing ruthenium-based complex: Cl2Ru(PCy3)(Py)2(3-phenylindenylidene) in good yield. This catalyst has been fully characterized and tested in ring-closing metathesis. Its moderate activity has been examined by kinetic studies using several substrates and different reaction conditions.
Found 
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