Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis
Publication type: Journal Article
Publication date: 2008-06-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of sulfur chelated dormant ruthenium olefin metathesis catalysts is presented. The catalysts prepared were shown to possess the uncommon cis-dichloro arrangement and were mostly inactive at room temperature. By systematically modifying the size of the substituent groups at the chelating sulfur atom, catalyst activity at different temperatures was significantly affected; more bulky substituents fomented activity at lower temperatures. The catalysts were also shown to be stable in solution and retained their catalytic activity even after being exposed to air for two weeks.
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Total citations:
90
Citations from 2024:
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(4.44%)
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GOST
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Kost T. et al. Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis // Journal of Organometallic Chemistry. 2008. Vol. 693. No. 12. pp. 2200-2203.
GOST all authors (up to 50)
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Kost T., Sigalov M., Goldberg I., Ben-Asuly A., Lemcoff N. G. Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis // Journal of Organometallic Chemistry. 2008. Vol. 693. No. 12. pp. 2200-2203.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.jorganchem.2008.03.028
UR - https://doi.org/10.1016/j.jorganchem.2008.03.028
TI - Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis
T2 - Journal of Organometallic Chemistry
AU - Kost, Tamar
AU - Sigalov, Mark
AU - Goldberg, Israel
AU - Ben-Asuly, Amos
AU - Lemcoff, N Gabriel
PY - 2008
DA - 2008/06/01
PB - Elsevier
SP - 2200-2203
IS - 12
VL - 693
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
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@article{2008_Kost,
author = {Tamar Kost and Mark Sigalov and Israel Goldberg and Amos Ben-Asuly and N Gabriel Lemcoff},
title = {Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis},
journal = {Journal of Organometallic Chemistry},
year = {2008},
volume = {693},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.jorganchem.2008.03.028},
number = {12},
pages = {2200--2203},
doi = {10.1016/j.jorganchem.2008.03.028}
}
Cite this
MLA
Copy
Kost, Tamar, et al. “Latent sulfur chelated ruthenium catalysts: Steric acceleration effects on olefin metathesis.” Journal of Organometallic Chemistry, vol. 693, no. 12, Jun. 2008, pp. 2200-2203. https://doi.org/10.1016/j.jorganchem.2008.03.028.