First P*,S-bidentate diamidophosphite ligand in Pd-catalyzed asymmetric reactions
Sergey V Zheglov
1
,
I D Firsin
1
,
Vladislav S Zimarev
1
,
Alexander V Maximychev
2
,
Alexander M. Perepukhov
2
,
N S Goulioukina
1, 3, 4
1
2
Publication type: Journal Article
Publication date: 2020-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
A novel P*,S-bidentate diamidophosphite ligand with a 1,3,2-diazaphospholidine core and an exocyclic thioether fragment provided up to 86% ee in the Pd-catalyzed alkylation of rac-(E)-1,3-diphenylallyl acetate with dimethyl malonate, as well as up to 73 and 75% ee in the amination of this substrate with pyrrolidine and diethyl (aminomethyl)phosphonate, respectively. For the Pd-catalyzed alkylation of cinnamyl acetate with β-keto esters, ee values up to 76% were achieved.
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12
Total citations:
12
Citations from 2024:
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(25%)
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Gavrilov K. N. et al. First P*,S-bidentate diamidophosphite ligand in Pd-catalyzed asymmetric reactions // Mendeleev Communications. 2020. Vol. 30. No. 1. pp. 31-33.
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Gavrilov K. N., Chuchelkin I. V., Zheglov S. V., Firsin I. D., Zimarev V. S., Gavrilov V. K., Maximychev A. V., Perepukhov A. M., Goulioukina N. S. First P*,S-bidentate diamidophosphite ligand in Pd-catalyzed asymmetric reactions // Mendeleev Communications. 2020. Vol. 30. No. 1. pp. 31-33.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.010
UR - https://doi.org/10.1016/j.mencom.2020.01.010
TI - First P*,S-bidentate diamidophosphite ligand in Pd-catalyzed asymmetric reactions
T2 - Mendeleev Communications
AU - Gavrilov, Konstantin N.
AU - Chuchelkin, Ilya V
AU - Zheglov, Sergey V
AU - Firsin, I D
AU - Zimarev, Vladislav S
AU - Gavrilov, Vladislav K
AU - Maximychev, Alexander V
AU - Perepukhov, Alexander M.
AU - Goulioukina, N S
PY - 2020
DA - 2020/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 31-33
IS - 1
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2020_Gavrilov,
author = {Konstantin N. Gavrilov and Ilya V Chuchelkin and Sergey V Zheglov and I D Firsin and Vladislav S Zimarev and Vladislav K Gavrilov and Alexander V Maximychev and Alexander M. Perepukhov and N S Goulioukina},
title = {First P*,S-bidentate diamidophosphite ligand in Pd-catalyzed asymmetric reactions},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2020.01.010},
number = {1},
pages = {31--33},
doi = {10.1016/j.mencom.2020.01.010}
}
Cite this
MLA
Copy
Gavrilov, Konstantin N., et al. “First P*,S-bidentate diamidophosphite ligand in Pd-catalyzed asymmetric reactions.” Mendeleev Communications, vol. 30, no. 1, Jan. 2020, pp. 31-33. https://doi.org/10.1016/j.mencom.2020.01.010.