Laboratory of Coordination Chemistry

1. Design and synthesis of hemilabile heterobidentate ligands 2. Comprehensive study of their coordination behavior with respect to transition metals 3. Study of the influence of ligand parameters and the type of its coordination on the activity and enantioselectivity of catalytic systems

• design and synthesis (without the use of phosphorus bases and trigalides) of bicycloamide phosphites (precursor ligands) and their dialkylphosphite derivatives as non-trivial, but at the same time affordable, modular and highly effective chirality inducers for asymmetric palladium catalysis processes; • development of an optimal strategy for the selective production of palladium complexes based on these ligands; • establishment of the structure of new compounds using modern methods of instrumental analysis and quantum chemical calculations; • ensuring the optimized use of the obtained ligands in the composition of in situ formed catalytic compositions, as well as individual complexes in asymmetric reactions of Pd-catalyzed allyl substitution.