Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction
3
Publication type: Journal Article
Publication date: 2022-07-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
New copper-containing organosilicon hybrid materials were synthesized by the reaction of branched polymethyl- silsesquioxane with copper nanoparticles prepared by the metal-vapor synthesis. Hybrid materials showed a high activity in the catalytic olefination of p -chlorobenzaldehyde hydrazone with polyhaloalkanes such as CBrCl 3 , CBr 4 and CF CBr to afford the corresponding halostyrenes in the yields above 80%. The structure and composition of the prepared nanocomposites were studied by X-ray using synchrotron radiation to show that the active sites of the catalysts are mixed copper(I)–copper(II) oxides (Cu–Cu 2 O–CuO) in nature.
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Total citations:
8
Citations from 2024:
2
(25%)
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GOST
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Vasilkov A. et al. Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 478-481.
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Vasilkov A., Migulin D. A., Muzalevskiy V. M., Naumkin A. V., Pereyaslavtsev A., Zubavichus Y. V., Nenajdenko V. G., Muzafarov A. M. Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction // Mendeleev Communications. 2022. Vol. 32. No. 4. pp. 478-481.
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TY - JOUR
DO - 10.1016/j.mencom.2022.07.016
UR - https://doi.org/10.1016/j.mencom.2022.07.016
TI - Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction
T2 - Mendeleev Communications
AU - Vasilkov, Alexander
AU - Migulin, Dmitry A
AU - Muzalevskiy, Vasiliy M
AU - Naumkin, Alexander V.
AU - Pereyaslavtsev, Alexander
AU - Zubavichus, Yan V.
AU - Nenajdenko, Valentine G.
AU - Muzafarov, Aziz M.
PY - 2022
DA - 2022/07/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 478-481
IS - 4
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2022_Vasilkov,
author = {Alexander Vasilkov and Dmitry A Migulin and Vasiliy M Muzalevskiy and Alexander V. Naumkin and Alexander Pereyaslavtsev and Yan V. Zubavichus and Valentine G. Nenajdenko and Aziz M. Muzafarov},
title = {Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jul},
url = {https://doi.org/10.1016/j.mencom.2022.07.016},
number = {4},
pages = {478--481},
doi = {10.1016/j.mencom.2022.07.016}
}
Cite this
MLA
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Vasilkov, Alexander, et al. “Copper-containing polymethylsilsesquioxane nanocomposites in catalytic olefination reaction.” Mendeleev Communications, vol. 32, no. 4, Jul. 2022, pp. 478-481. https://doi.org/10.1016/j.mencom.2022.07.016.