pH-Dependent molecular switch based on Pv porphyrin
Inessa A. Efimova
1
,
Gayane Kirakosyan
1, 2
,
Aslan Yu. Tsivadze
1, 2
,
Aslan Tsivadze
1, 2
,
Yulia G. Gorbunova
1, 2
Publication type: Journal Article
Publication date: 2024-03-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Water-soluble phosphorus(v) porphyrin with p-amino- phenoxy groups as axial ligands was obtained, and its photophysical and photochemical properties were investigated and rationalized using quantum chemical calculations. It was demonstrated that at pH ≥ 6.1 this porphyrin did not emit or generate singlet oxygen, whereas at pH ≤ 2.0 it completely converted into the N-protonated form, which exhibited fluorescence and the ability to generate singlet oxygen.
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Total citations:
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Citations from 2024:
2
(100%)
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Efimova I. A. et al. pH-Dependent molecular switch based on Pv porphyrin // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 167-169.
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Efimova I. A., Safonova E. A., Polovkova M. A., Martynov A. G., Kirakosyan G., Tsivadze A. Y., Tsivadze A., Gorbunova Y. G. pH-Dependent molecular switch based on Pv porphyrin // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 167-169.
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RIS
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.003
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943624000610
TI - pH-Dependent molecular switch based on Pv porphyrin
T2 - Mendeleev Communications
AU - Efimova, Inessa A.
AU - Safonova, Evgeniya A.
AU - Polovkova, Marina A
AU - Martynov, Alexander G.
AU - Kirakosyan, Gayane
AU - Tsivadze, Aslan Yu.
AU - Tsivadze, Aslan
AU - Gorbunova, Yulia G.
PY - 2024
DA - 2024/03/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 167-169
IS - 2
VL - 34
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2024_Efimova,
author = {Inessa A. Efimova and Evgeniya A. Safonova and Marina A Polovkova and Alexander G. Martynov and Gayane Kirakosyan and Aslan Yu. Tsivadze and Aslan Tsivadze and Yulia G. Gorbunova},
title = {pH-Dependent molecular switch based on Pv porphyrin},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943624000610},
number = {2},
pages = {167--169},
doi = {10.1016/j.mencom.2024.02.003}
}
Cite this
MLA
Copy
Efimova, Inessa A., et al. “pH-Dependent molecular switch based on Pv porphyrin.” Mendeleev Communications, vol. 34, no. 2, Mar. 2024, pp. 167-169. https://linkinghub.elsevier.com/retrieve/pii/S0959943624000610.