Medium viscosity effect on fluorescent properties of Sn(IV)-tetra(4-sulfonatophenyl)porphyrin complexes in buffer solutions
Publication type: Journal Article
Publication date: 2019-03-01
scimago Q1
wos Q1
SJR: 0.935
CiteScore: 10.5
Impact factor: 5.2
ISSN: 01677322, 18733166
Materials Chemistry
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract
Supramolecular triads consisting of hydrophilic Sn(IV)-tetra(4-sulfophenyl)-porphyrin and two axial guests such as propylphenol, tyrosine, and 2-(2-hydroxyphenyl)-benzoxazole were synthesized. The structures of synthesized complexes were identified by experimental spectroscopic and quantum-chemical simulation methods, and their fluorescent properties were studied in various viscosity media (mixed phosphate buffer-glycerin solvents of different composition). The effect of axial ligand structure on the fluorescent properties of these triads (due to the hydrogen bonding or π-π stacking between the components of «host-guest» systems) is discussed. The potential use of synthesized complexes as environmental probes of local viscosity is proposed.
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Citations from 2024:
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Mamardashvili N. et al. Medium viscosity effect on fluorescent properties of Sn(IV)-tetra(4-sulfonatophenyl)porphyrin complexes in buffer solutions // Journal of Molecular Liquids. 2019. Vol. 277. pp. 1047-1053.
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Mamardashvili N., Maltceva O. V., Lazovskiy D. A., Borovkov V., Khodov I. A., Koifman O. I. Medium viscosity effect on fluorescent properties of Sn(IV)-tetra(4-sulfonatophenyl)porphyrin complexes in buffer solutions // Journal of Molecular Liquids. 2019. Vol. 277. pp. 1047-1053.
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TY - JOUR
DO - 10.1016/j.molliq.2018.12.118
UR - https://doi.org/10.1016/j.molliq.2018.12.118
TI - Medium viscosity effect on fluorescent properties of Sn(IV)-tetra(4-sulfonatophenyl)porphyrin complexes in buffer solutions
T2 - Journal of Molecular Liquids
AU - Mamardashvili, N.Zh.
AU - Maltceva, Olga V
AU - Lazovskiy, Dmitriy A
AU - Borovkov, Victor
AU - Khodov, Ilya A.
AU - Koifman, Oskar I.
PY - 2019
DA - 2019/03/01
PB - Elsevier
SP - 1047-1053
VL - 277
SN - 0167-7322
SN - 1873-3166
ER -
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@article{2019_Mamardashvili,
author = {N.Zh. Mamardashvili and Olga V Maltceva and Dmitriy A Lazovskiy and Victor Borovkov and Ilya A. Khodov and Oskar I. Koifman},
title = {Medium viscosity effect on fluorescent properties of Sn(IV)-tetra(4-sulfonatophenyl)porphyrin complexes in buffer solutions},
journal = {Journal of Molecular Liquids},
year = {2019},
volume = {277},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.molliq.2018.12.118},
pages = {1047--1053},
doi = {10.1016/j.molliq.2018.12.118}
}