Organic Electronics, volume 56, pages 208-215

Synthesis, luminescence and charge transport properties of furan/phenylene co-oligomers: The study of conjugation length effect

Beloborodova Alina 1
Kuimov Anatoly D 1
Koskin Igor P. 1
Frantseva Ekaterina S 1
Rybalova Tatyana V. 1
Shundrina Inna K. 1
Becker Christina S 1
Publication typeJournal Article
Publication date2018-05-01
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor3.2
ISSN15661199
Materials Chemistry
General Chemistry
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering
Biomaterials
Abstract
Heteroaryl-containing co-oligomers are considered among the most promising materials for organic optoelectronics. In this work we synthesized a series of linear furan/phenylene co-oligomers (FPs) with different molecular length and studied their structure, luminescence and charge transport properties. The X-ray diffraction experiments revealed the higher distortion of molecular planarity for the longer FPs which is assigned to the crystal environment effect. All FPs demonstrated stability and high photoluminescence quantum yield (PL QY) both in solution and vapor-grown single crystals. The absolute PL QY as high as 70% was demonstrated for FP6 single crystal. The top-contact top-gate organic field-effect transistors (OFETs) demonstrated virtually the same mobility ∼0.35 cm2/Vs for a FPs with different conjugation chain. However the threshold voltage for the studied OFETs was demonstrated to be significantly reduced for a co-oligomer FP7 with longer conjugation chain. Thus we conclude that the increase of conjugation chain for co-oligomers does not benefit an increase of charge carrier mobility but improve the crystal/dielectric interface.

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Kazantsev M. S. et al. Synthesis, luminescence and charge transport properties of furan/phenylene co-oligomers: The study of conjugation length effect // Organic Electronics. 2018. Vol. 56. pp. 208-215.
GOST all authors (up to 50) Copy
Kazantsev M. S., Beloborodova A., Kuimov A. D., Koskin I. P., Frantseva E. S., Rybalova T. V., Shundrina I. K., Becker C. S., Mostovich E. A. Synthesis, luminescence and charge transport properties of furan/phenylene co-oligomers: The study of conjugation length effect // Organic Electronics. 2018. Vol. 56. pp. 208-215.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.orgel.2018.01.010
UR - https://doi.org/10.1016%2Fj.orgel.2018.01.010
TI - Synthesis, luminescence and charge transport properties of furan/phenylene co-oligomers: The study of conjugation length effect
T2 - Organic Electronics
AU - Kazantsev, Maxim S.
AU - Beloborodova, Alina
AU - Kuimov, Anatoly D
AU - Koskin, Igor P.
AU - Frantseva, Ekaterina S
AU - Rybalova, Tatyana V.
AU - Shundrina, Inna K.
AU - Becker, Christina S
AU - Mostovich, Evgeny A.
PY - 2018
DA - 2018/05/01 00:00:00
PB - Elsevier
SP - 208-215
VL - 56
SN - 1566-1199
ER -
BibTex
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BibTex Copy
@article{2018_Kazantsev,
author = {Maxim S. Kazantsev and Alina Beloborodova and Anatoly D Kuimov and Igor P. Koskin and Ekaterina S Frantseva and Tatyana V. Rybalova and Inna K. Shundrina and Christina S Becker and Evgeny A. Mostovich},
title = {Synthesis, luminescence and charge transport properties of furan/phenylene co-oligomers: The study of conjugation length effect},
journal = {Organic Electronics},
year = {2018},
volume = {56},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016%2Fj.orgel.2018.01.010},
pages = {208--215},
doi = {10.1016/j.orgel.2018.01.010}
}
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