Effect of cyclodextrins on the electrochemical behaviour of ascorbic acid on gold electrodes
Тип публикации: Journal Article
Дата публикации: 1996-05-01
scimago Q1
wos Q1
БС1
SJR: 0.76
CiteScore: 8.1
Impact factor: 4.1
ISSN: 15726657, 18732569
General Chemical Engineering
Analytical Chemistry
Electrochemistry
Краткое описание
The study of the inclusion complexes formed by ascorbic acid with β-cyclodextrin at different pH is reported. Special attention is paid to the electrochemical behaviour of ascorbic acid in the presence of the macrocycle on gold electrodes. The modifications observed can be explained by the decrease in the diffusion coefficient of the complex and the presence of an additional chemical step, the dissociation of the complex prior to the electron transfer steps. The inclusion of ascorbic acid in β-cyclodextrin increases the stability of the guest molecule to oxidising agents. Adsorption of β-cyclodextrin on gold is also detected, depending on the pH. No effect of ascorbic acid behaviour owing to the addition of α-cyclodextrin was observed.
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Manzanares M. I., Solis V., de Rossi R. H. Effect of cyclodextrins on the electrochemical behaviour of ascorbic acid on gold electrodes // Journal of Electroanalytical Chemistry. 1996. Vol. 407. No. 1-2. pp. 141-147.
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Manzanares M. I., Solis V., de Rossi R. H. Effect of cyclodextrins on the electrochemical behaviour of ascorbic acid on gold electrodes // Journal of Electroanalytical Chemistry. 1996. Vol. 407. No. 1-2. pp. 141-147.
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TY - JOUR
DO - 10.1016/0022-0728(95)04468-X
UR - https://doi.org/10.1016/0022-0728(95)04468-X
TI - Effect of cyclodextrins on the electrochemical behaviour of ascorbic acid on gold electrodes
T2 - Journal of Electroanalytical Chemistry
AU - Manzanares, M I
AU - Solis, V
AU - de Rossi, Rita H.
PY - 1996
DA - 1996/05/01
PB - Elsevier
SP - 141-147
IS - 1-2
VL - 407
SN - 1572-6657
SN - 1873-2569
ER -
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@article{1996_Manzanares,
author = {M I Manzanares and V Solis and Rita H. de Rossi},
title = {Effect of cyclodextrins on the electrochemical behaviour of ascorbic acid on gold electrodes},
journal = {Journal of Electroanalytical Chemistry},
year = {1996},
volume = {407},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0022-0728(95)04468-X},
number = {1-2},
pages = {141--147},
doi = {10.1016/0022-0728(95)04468-X}
}
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MLA
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Manzanares, M. I., et al. “Effect of cyclodextrins on the electrochemical behaviour of ascorbic acid on gold electrodes.” Journal of Electroanalytical Chemistry, vol. 407, no. 1-2, May. 1996, pp. 141-147. https://doi.org/10.1016/0022-0728(95)04468-X.